Updated on 2024/03/16

写真a

 
TANAKA Hideki
 
Organization
Faculty of Science and Engineering Professor
Other responsible organization
Applied Chemistry Course of Graduate School of Science and Engineering, Master's Program
Applied Chemistry Course of Graduate School of Science and Engineering, Doctoral Program
External link

Degree

  • 博士(理学) ( 東京大学 )

  • 修士(理学) ( 東京大学 )

Education

  • 1997.3
     

    The University of Tokyo   Graduate School, Division of Science   doctor course   completed

  • 1994.3
     

    The University of Tokyo   Graduate School, Division of Science   master course   completed

  • 1992.3
     

    The University of Tokyo   Faculty of Science   graduated

  • 1988.3
     

    岐阜県立多治見北高等学校   graduated

Research History

  • 2006.4 - 2015.3

    東京大学・非常勤講師

  • 2011.4 -  

    中央大学理工学部教授

  • 2007.4 - 2011.3

    中央大学理工学部准教授

  • 2004.4 - 2007.3

    中央大学理工学部助教授

  • 1997.10 - 2004.3

    理化学研究所・研究員

  • 1997.4 - 1997.9

    日本学術振興会特別研究員(PD)(東京大学大学院理学系研究科)

  • 1996.4 - 1997.3

    日本学術振興会奨励研究員(DC)(東京大学大学院理学系研究科)

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Professional Memberships

  • 日本化学会

  • フラーレン研究会

  • 理研レビュー編集委員会

  • 超微粒子とクラスター懇談会

  • 国際会議「5th RIKEN International Conference」実行委員会(委員)

  • American Association for Aerosol Research(AAAR)

  • GAeF (Gesellschaft fuer Aerosolforschung e. V.)

  • 日本化学会関東支部

  • Japan Society of Molecular Science

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Research Interests

  • Nanoscience

Research Areas

  • Nanotechnology/Materials / Nanometer-scale chemistry  / Nanostructural chemistry

Papers

  • Catalytic Activity of Nonaggregating Cu Nanoparticles Supported in Pores of Zeolite for Aerobic Oxidation of Benzyl Alcohol Reviewed

    Shunya Sakane, Kai Akimoto, Kishin Konishi, Kenta Takaoka, Harunobu Iwatsuki, Mayu Akutsu, Toshiki Sugai, Hideki Tanaka

    ACS Omega   9 ( 1 )   970 - 976   2023.12

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsomega.3c07156

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  • Plasmonic Heating of Copper Nanoparticles with Thermoresponsive Polymers Reviewed

    Shunya Sakane, Toshiki Anji, Itsuki Yamagishi, Issei Kohara, Hideki Tanaka

    Chemistry Letters   52 ( 7 )   582 - 585   2023.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Oxford University Press (OUP)  

    DOI: 10.1246/cl.230174

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  • Thermoelectric Properties of PEDOT:PSS Containing Connected Copper Selenide Nanowires Synthesized by the Photoreduction Method Reviewed

    Shunya Sakane, Shunichiro Miwa, Tatsuki Miura, Kazuki Munakata, Takafumi Ishibe, Yoshiaki Nakamura, Hideki Tanaka

    ACS Omega   7   32101 - 32107   2022.9

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    DOI: 10.1021/acsomega.2c03335

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  • Plasmonic Photoluminescence of Cu Nanoparticle Realized by Molecular Optical Antenna Designed on Nanosheets Reviewed

    Masaya Miyagawa, Kengo Nishio, Akane Shibusawa, Hitomi Kotake, Hideki Tanaka

    Chemistry Letters   51   500 - 503   2022.3

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.220037

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  • Environmental-friendly degradation of clay-hybridized Cu nanoparticles by carboxylic acids Reviewed

    Masaya Miyagawa, Yoko Ikeyama, Hitomi Kotake, Toshiki Maeda, Hideki Tanaka

    Chemical Physics Letters   753   137615 - 137615   2020.8

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    DOI: 10.1016/j.cplett.2020.137615

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  • Photoluminescent Cu nanoparticles induced by energy transfer on saponite nanosheet Reviewed

    K. Nishio, M. Miyagawa, H. Tanaka

    Clay Science   23   67 - 71   2019.12

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  • Aqueous synthesis of protectant-free copper nanocubes by a disproportionation reaction of Cu2O on synthetic saponite Reviewed

    Masaya Miyagawa, Miharu Usui, Yu Imura, Shota Kuwahara, Toshiki Sugai, Hideki Tanaka

    Chemical Communications   54   8454 - 8457   2018.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C8CC03182G

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  • Synthesis of Truffle-shaped Oxide-free Cu Nanoparticles under Atmospheric Conditions with the Aid of Photocatalytic TiO2 Reviewed

    Masaya Miyagawa, Takuya Aoki, Ryoya Seki, Akane Shibusawa, Hideki Tanaka

    CHEMISTRY LETTERS   46 ( 9 )   1403 - 1405   2017.9

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    Truffle-shaped Cu nanoparticles (NPs) were synthesized by photoreduction of copper acetate solution in the presence of TiO2. X-ray diffraction measurement revealed that the obtained NPs were composed of pure Cu without oxides, which was notable because the photoirradiation was performed under atmospheric conditions, where the Cu NPs are easily oxidized. The Cu NPs were dispersed stably without protectants because the TiO2 NPs adsorbed on the Cu NPs were dispersed, probably due to their electric repulsion.

    DOI: 10.1246/cl.170564

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  • Diameter-controlled Cu nanoparticles on saponite and preparation of film by using spontaneous phase separation Reviewed

    Masaya Miyagawa, Akane Shibusawa, Kaho Maeda, Akiyoshi Tashiro, Toshiki Sugai, Hideki Tanaka

    RSC ADVANCES   7 ( 66 )   41896 - 41902   2017

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Cu nanoparticles have attracted much attention due to their optical, catalytic, and electrical properties. Their syntheses, however, have required hazardous reducing agents. In addition, they are easily oxidized, which destroys their properties. It has also not been possible to control the diameter and the dispersibility for further applications in functional materials. To solve these problems, we have recently synthesized oxide-free Cu nanoparticles adsorbed on kaolinite, a non-dispersive layered clay, by environmentally friendly photoreduction. Focusing on the layer charge of the clay, we report diameter-and dispersibility-controlled Cu nanoparticles on saponite, a dispersive clay, in the present study. The obtained oxide-free Cu nanoparticles were stable under N-2 atmosphere, while they exhibited a fast back reaction to Cu2+ upon exposure to fresh air. The diameter of the Cu nanoparticles could be controlled simply with [Cu2+], because Cu2+ was adsorbed on saponite before the photoreduction. The dispersibility of the Cu nanoparticles was controlled without changing the diameter using the size of saponite aggregates: these were stably dispersed at low [Cu2+], and flocculated at high [Cu2+]. The flocculates could be collected by filtration and the obtained viscous paste was useful for preparing a film with the optical properties of the Cu nanoparticles without aggregation. Therefore, the present study revealed that combining the adsorption of Cu2+ on saponite with photoreduction is a novel and environmentally friendly synthetic method for controlling the diameter and the dispersibility of Cu nanoparticles, and it has the potential to further their applications in functional materials.

    DOI: 10.1039/c7ra08659h

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  • Lustrous copper nanoparticle film: Photodeposition with high quantum yield and electric conductivity Reviewed

    Masaya Miyagawa, Mari Yonemura, Hideki Tanaka

    Chemical Physics Letters   665   95   2016.10

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  • Precious metal-like oxide-free copper nanoparticles: high oxidation resistance and geometric structure Reviewed

    Masaya Miyagawa, Toshiki Maeda, Ryo Tokuda, Akane Shibusawa, Takuya Aoki, Kazu Okumura, Hideki Tanaka

    RSC ADVANCES   6 ( 106 )   104560 - 104565   2016

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    Cu nanoparticles have attracted much attention as an alternative to precious metal Au- and Pt-based materials. However, they have a problem with stability and get oxidized easily. Moreover, their synthesis is carried out with hazardous chemicals and in conditions, which is not environmentally friendly. Thus, both improvement in oxidation resistance and establishment of a novel synthesis method under mild conditions are desired for further applications. To solve these problems, we synthesized Cu nanoparticles from copper(II) acetate by photoreduction at room temperature in the presence of kaolinite, a layered clay mineral with high gas barrier properties. We obtained disk-like metallic Cu nanoparticles adsorbed on kaolinite without oxides. The nanoparticles showed high oxidation resistance in the solid phase. The powder sample was stable and did not get oxidized at all even after 6 months on exposure to fresh air in spite of no apparent protectants, which was revealed by infrared spectroscopy. Namely, the obtained Cu nanoparticles showed a precious metal-like property. On the other hand, the as-prepared Cu nanoparticles still showed the reactivity with fresh air in the suspension. This indicates that the adsorption on kaolinite did not spoil the reactivity of the Cu nanoparticles. Therefore, the present study revealed that the combination of photoreduction and addition of a layered clay mineral would be a promising environmentally friendly way to synthesize oxidation-resistant metal nanoparticles.

    DOI: 10.1039/c6ra18076k

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  • Oxidation-resistive copper nanoparticles: photoreduction synthesis and their oxidation state measurements by XAFS and HRTEM Reviewed

    H. Tanaka, T. Aoki, M. Yonemura, M. Miyagawa, K. Okumura

    16TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS16)   712   012120   2016

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    We examined the synthesis of copper nanoparticles by photoreduction, and characterized them using optical spectroscopy, XAFS measurement, and electron microscopy. Ethanol solution of copper acetate with TiO2 nanoparticles was photoirradated. Optical absorption observation indicated that copper nanoparticles were formed in the solution. XAFS measurement indicated that the nanoparticles were metallic, not oxidized. Electron microscopy observation exhibited that the nanoparticles kept metallic even under exposure to air.

    DOI: 10.1088/1742-6596/712/1/012120

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  • Intense Plasmon-induced Cotton Effects in Colloidal Silver Triangular Nanoplates Synthesized by a Ligand-exchange Process Reviewed

    Naoki Nishida, Yasuhiro Kojima, Hideki Tanaka

    CHEMISTRY LETTERS   43 ( 8 )   1227 - 1229   2014.8

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    Chiroptically active Ag triangular nanoplates were synthesized by the ligand-exchange reaction of achiral Ag nanoplates with chiral D- or L-penicillamine molecules. Analysis of the chiroptical properties of the synthesized nanoplates by circular dichroism spectroscopy revealed intense Cotton effects, with wavelengths that corresponded to those of the surface plasmon resonances for the nanoplates. Enantiomeric excess and pH dependence of these effects were also measured to explore the origin of the chiroptical activity of the nanoplates.

    DOI: 10.1246/cl.140317

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  • Production of Oxidation-resistant Copper Nanoparticles on Carbon Nanotubes by Photoreduction Reviewed

    Naoki Nishida, Akira Miyashita, Tatsuya Tsukuda, Hideki Tanaka

    CHEMISTRY LETTERS   42 ( 2 )   168 - 170   2013.2

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    Copper nanoparticles (Cu NPs) were produced through photoreduction of a mixture of copper acetate solution and carbon nanotubes (CNTs) at room temperature. The diameter of the NPs could be controlled by the photoirradiation time. HRTEM and XRD measurements revealed that the NPs were composed of a metallic Cu core and a Cu2O shell that acts as a passive layer.

    DOI: 10.1246/cl.2013.168

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  • Chiral Glutathione-protected Ag Triangular Nanoplates Synthesized by Protectant-substitution Reaction: Chiroptical and Surface Structure Analysis Reviewed

    Naoki Nishida, Yasuhiro Kojima, Hideki Tanaka

    CHEMISTRY LETTERS   41 ( 9 )   926 - 928   2012.9

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    Chiral Ag:SG (glutathione) triangular nanoplates were synthesized by substitution reaction of achiral Ag:poly(vinylpyrrolidone) (PVP) nanoplates with glutathione free GSH molecules. Analysis of the chiroptical properties of the synthesized nanoplates using a circular dichroism spectrometer revealed characteristic Cotton effects with wavelengths that corresponded well to those of plasmon resonances for Ag nanoplates. X-ray photoelectron spectrometry analysis of their chemical compositions revealed that complete substitution of PVP molecules with GSH molecules proceeds on the nanoplates.

    DOI: 10.1246/cl.2012.926

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  • Regenerative synthesis of copper nanoparticles|rn|by photoirradiation Reviewed

    N. Nishida, A. Miyashita, N. Hashimoto, H. Murayama, H. Tanaka

    The European Physical Journal D   63   307   2011.4

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  • Stable Transport of Gas-born Ag Nanoparticles into Liquid Phase Mediated by Poly(vinylpyrrolidone) Molecules Reviewed

    Naomi Hashimoto, Naoki Nishida, Haruno Murayama, Hideki Tanaka

    CHEMISTRY LETTERS   40 ( 2 )   144 - 146   2011.2

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    We demonstrate that gas-born nanoparticles can be transported into solution successfully. Our results show that Ag nanoparticles produced in gas phase are introduced into poly(vinylpyrrolidone) solution without structural changes such as nanoparticle aggregation. It is also shown that Ag nanoparticles in solution show surface plasmon resonance, suggesting that the optical properties of nanoparticles are not impaired by the transport from gas to liquid.

    DOI: 10.1246/cl.2011.144

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  • Number-adjustable nanoparticle clusters realized by a combination of Ag|rn|and C60 nanoparticles in the gas phase Reviewed

    Hideki Tanaka, Futoshi Maeda

    Chemical Physics Letters   484   37 - 40   2009.10

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  • Ag triangular nanoplates synthesized by photo-induced reduction: Structure analysis and stability Reviewed

    Haruno Murayama, Naomi Hashimoto, Hideki Tanaka

    Chemical Physics Letters   482 ( 4-6 )   291 - 295   2009

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    Ag triangular nanoplates were synthesized by photoirradiation to AgNO3 ethanol solution in the presence of polyvinylpyrrolidone (PVP) under anaerobic conditions at room temperature. High-resolution SEM and TEM observations revealed that thin Ag equilateral triangular nanoplates, each of which was a single crystal with sharp corners and flat faces presented by {1 1 1} planes, were produced. Analyses of XAFS and XPS have shown that these nanoplates are protected by coordination of O atoms in PVP molecules, not being oxidized as Ag2O. The nanoplates are inherently stable, though they were easily truncated and dissolved if mixed with oxygen or water. © 2009 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.cplett.2009.10.015

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  • Growth Process of Ag Triangular Nanoplates Observed by In Situ XAFS Reviewed

    H. Murayama, N. Hashimoto, H. Tanaka

    14TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS14), PROCEEDINGS   190   012132   2009

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    We examined to establish the simple synthesis method of Ag triangular nanoplates in order to elucidate their growth process. Ethanol solution of AgNO3 was photoirradiated without reduction agents except in the presence of PVP, poly(vinil-pyrrolidone). Electron microscope observations revealed that the shape of the product was Ag triangular nanoplates with sharp corners and a flat face. In situ XAFS and optical absorption measurements suggested that the Ag triangular nanoplates were photoinduced-converted from Ag spherical nanoparticles via Ag truncated triangular nanoplates.

    DOI: 10.1088/1742-6596/190/1/012132

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  • Production of nanoparticles composed of ionic liquid [C4.mpyrr][NTf2] and their chemical identification by diameter analysis and X-ray photoelectron spectroscopy Reviewed

    Masaharu Shigeyasu, Haruno Murayama, Hideki Tanaka

    Chemical Physics Letters   384   283 - 287   2008.10

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  • Production of nanoparticles composed of ionic liquid [C(4)mpyrr][NTf(2)] and their chemical identification by diameter analysis and X-ray photoelectron spectroscopy Reviewed

    Masaharu Shigeyasu, Haruno Murayama, Hideki Tanaka

    CHEMICAL PHYSICS LETTERS   463 ( 4-6 )   373 - 377   2008.10

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER SCIENCE BV  

    Production of nanoparticles composed of ionic liquid [C(4)mpyrr][NTf(2)], N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide, was demonstrated by a gas aggregation technique under low pressure. The diameter spectra were measured by a differential mobility analyzer (DMA) and were dependent on the heating temperature. Photoelectron spectra for the nanoparticles diameter-selected at 10 nm were also measured by X-ray photoelectron spectroscopy (XPS), and their chemical composition and structure were identified by comparison with photoelectron spectra for neat ionic liquid. The form and surface structure of the nanoparticles deposited onto an Au-coated Si substrate were also determined. (C) 2008 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.cplett.2008.08.068

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  • Production of small Ag-containing C-60 nanoparticles under atmospheric condition Reviewed

    Naomi Hashimoto, Haruno Murayama, Hideki Tanaka

    JAPANESE JOURNAL OF APPLIED PHYSICS   47 ( 6 )   4777 - 4779   2008.6

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    Ag-containing C-60 nanoparticles were produced from Ag vapor interacting with C60 nanoparticles formed by C60 vapor. The particle diameter of the produced nanoparticles was measured using a differential mobility analyzer (DMA). The particle diameter dependence on the Ag vapor temperature was also measured using the DMA. The chemical composition of the produced nanoparticles was investigated by X-ray photoelectron spectroscopy. The experimental results indicated that the C60 nanoparticles worked prominently as a supporting nanomaterial for the Ag nanoparticles.

    DOI: 10.1143/JJAP.47.4777

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  • Diameter determination of C-60 and C-70 monomers in the gas phase using a differential mobility analyzer Reviewed

    H Tanaka, K Takeuchi

    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING   80 ( 4 )   759 - 761   2005.2

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    C-60 and C-70 monomers were produced by sublimation of fullerene powder under low-pressure conditions, and their electrical mobilities were measured using a differential mobility analyzer. Apparent particle diameter was estimated from the electrical mobility using Stokes law of resistance. Actual particle diameter is discussed herein in the framework of the kinetic theory of gases. The estimated particle diameter is compared with the particle diameter estimated from its crystal structure.

    DOI: 10.1007/s00339-004-2946-x

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  • Structure identification of a C-60 dimer using electrical mobility measurements Reviewed

    H Tanaka, K Takeuchi

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS   43 ( 7A )   4462 - 4463   2004.7

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    C-60 particles were formed by a C-60 vapor source equipped with an Am-241 ionizer, and their mobility was measured using a differential mobility analyzer (DMA). Two distinct peaks for the C-60 monomer and the C-60 dimer were observed in the mobility spectra. When the measured mobility was compared with theoretical mobilities for several isomers of the C-60 dimer, the C-60 dimer was suggested to have the geometric structure of a [2+2] 66/66 cycloadduct C-60 dimer. Selective formation of the [2+2] C-60 dimer was also suggested when the peak profile for the C-60 dimer was analyzed using the transfer function for the DMA. The formation mechanism of the [2+2] C-60 dimer in the gas phase is discussed.

    DOI: 10.1143/jjap.43.4462

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  • Highly oxygenated fullerene anions C60On- formed by corona discharge ionization in the gas phase Reviewed

    Hideki Tanaka, Kazuo Takeuchi, Yuichi Negishi, Tatsuya Tsukuda

    Chemical Physics Letters   384   283 - 287   2003.12

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  • Experimental transfer function for a low-pressure differential mobility analyzer by use of a monodisperse C-60 monomer Reviewed

    H Tanaka, K Takeuchi

    JOURNAL OF AEROSOL SCIENCE   34 ( 9 )   1167 - 1173   2003.9

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:PERGAMON-ELSEVIER SCIENCE LTD  

    A C-60 monomer as an inherently monodisperse standard particle was produced by a C-60 vapor source equipped with an Am-241 neutralizer, and its mobility spectrum was measured by using a low-pressure differential mobility analyzer (LPDMA). The transfer function was derived from the mobility spectrum and was measured as dependences on aerodynamic and electrodynamic conditions. The experimental transfer function thus obtained was compared with the theoretical transfer function. (C) 2003 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/S0021-8502(03)00093-4

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  • Photo-induced reactions of hemin(+)(DMSO)n clusters (n=0-3) produced with electrospray ionization Reviewed

    S Nonose, H Tanaka, N Okai, T Shibakusa, K Fuke

    EUROPEAN PHYSICAL JOURNAL D   20 ( 3 )   619 - 626   2002.9

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    Photo-induced reaction of [Fe(III)-protoporphyrin](+) (hemin(+)) ions solvated with dimethylsulfoxide (DMSO) is investigated by using a tandem mass spectrometer with electrospray ionization. We measure the photodissociation yields of mass-selected hemin(+)(DMSO)(n) clusters for n = 0-3 in the energy region of 15 800-28 200 cm(-1). The mass spectra of the fragment ions show the beta-cleavage of carboxymethyl groups in addition to the evaporation of solvent molecules. Yield of the beta-cleavage reaction is found to depend strongly on the excitation energy and the number of solvent molecules. We also examine the metastable decomposition of the clusters following primary mass selection and determine the incremental solvent binding energies and internal energies for the clusters using evaporative ensemble model. From these results, we investigate the reaction mechanism of beta-cleavage of hemin(+) ion.

    DOI: 10.1140/epjd/e2002-00153-8

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  • Investigation of SixC60 by in situ X-ray photoelectron spectroscopy Reviewed

    H. Tanaka, J. Onoe, T. Hara, K. Takeuchi

    5th RIKEN International Conference on Coherent Control in Matter   18   2002.4

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  • DMA(微分型静電分級器)を用いたナノ粒子計測とサイズ選別

    武内一夫, 田中秀樹, 藪本淳輔

    電子材料   41 ( 2 )   96 - 100   2002.2

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    Language:Japanese   Publisher:日本ポリテック株式会社  

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  • C-60 monomer as an inherently monodisperse standard nanoparticle in the 1 nm range Reviewed

    H Tanaka, K Takeuchi

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS   41 ( 2A )   922 - 924   2002.2

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:INST PURE APPLIED PHYSICS  

    A C-60 monomer was produced by evaporation of C-60 powder under low-pressure conditions, and its mobility spectrum was observed using a low-pressure differential mobility analyzer (LPDMA). Pressure dependence for the C-60 monomer in the spectrum was measured in order to examine the influence of C-60 aggregates on the peak profile of the C-60 monomer. Taking into account the diameter of the collision partner Ar atom, the diameter of the C-60 monomer was estimated in the framework of Stokes' law.

    DOI: 10.1143/JJAP.41.922

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  • In situ XPS study of Si-deposited C60 thin films Reviewed

    H. Tanaka, J. Onoe, K. Takeuchi

    Transactions of the Materials Research Society of Japan   26 ( 4 )   1175 - 1178   2001.12

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  • Investigation of Si-coated C60 Reviewed

    H. Tanaka, J. Onoe, T. Hara, K. Takeuchi

    RIKEN Review   ( 33 )   41 - 43   2001.3

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  • XPS Study of SixC60 Thin Films Reviewed

    H. Tanaka, J. Onoe, T. Hara, K. Takeuchi

    Transactions of the Materials Research Society of Japan   25 ( 4 )   1045 - 1047   2000.12

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  • Si含有C60 薄膜を用いた新規フラーレン化合物の合成 Reviewed

    田中秀樹, 尾上順, 原寿樹, 武内一夫

    超微粒子とクラスター懇談会 研究会講演論文集   ( 4 )   139 - 141   2000.5

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:超微粒子とクラスター懇談会  

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  • In situ Fourier-transform infrared study of electron-irradiation-induced reaction in a C-60 film Reviewed

    T Hara, J Onoe, H Tanaka, YZ Li, K Takeuchi

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS   39 ( 4A )   1872 - 1876   2000.4

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:JAPAN J APPLIED PHYSICS  

    The reaction between C-60 molecules in a 3-keV electron-irradiated C-60 thin film has been studied using in situ Fourier-transform infrared (FTIR) spectroscopy and ex situ laser-desorption FT-mass spectrometry (LD-FTMS). The results of FTIR and LD-FTMS measurements indicate that coalesced C-120 species were formed as a main product in the electron-beam (EB)-irradiated film. We studied the kinetics of the reaction by examining the decrease in the amount of C-60 molecules as a function of irradiation time and found that the reaction rate exhibits a linear dependence on the reactant concentration and a third-power dependence on the electron dose rate.

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  • Investigation of the interaction between C-60 and Si atoms Reviewed

    H Tanaka, J Onoe, T Hara, A Nakao, K Takeuchi

    MOLECULAR CRYSTALS AND LIQUID CRYSTALS   340   701 - 705   2000

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:GORDON BREACH SCI PUBL LTD  

    The interaction between C-60 and Si atoms was investigated using X-ray photoelectron spectroscopy (XPS) for the photo-irradiated Si-deposited C-60 film in order to establish a method of a synthesis for the Si-coated C-60 It was found that the C1s spectrum of the photo-irradiated film contains a peak due to C-Si bonding, while no peak due to C-SI bonding was observed for the film before photo-irradiation. This indicates that Si atoms stick to C-60 when using the present method.

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  • In situ FT-IR study of an electron-beam induced reaction of C-60 film Reviewed

    T Hara, J Onoe, H Tanaka, K Takeuchi

    MOLECULAR CRYSTALS AND LIQUID CRYSTALS   340   695 - 700   2000

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    The structural modification induced by electron-beam (EB) in a C-60 film and its kinetics have been studied using in situ high-resolution FT-IR spectroscopy. Similar to studies on photoirradiated KxC60 film, it was found that a coalescence reaction between adjacent C-60 molecules takes place, In order to investigate the interaction between an incident electron and C-60 molecules, the time-dependence of the amounts of C-60 On the EB irradiation was examined. It was found that the reaction rate exhibits a linear dependence on the reactant concentration and nonlinear dependence on the incident current.

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  • Formation process of Si-coated C-60 Reviewed

    H Tanaka, S Osawa, J Onoe, K Takeuchi

    JOURNAL OF PHYSICAL CHEMISTRY B   103 ( 29 )   5939 - 5942   1999.7

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    The formation process of Si-coated C-60, C60Sin (n = 1-60), was theoretically investigated by examining both the geometric structure and standard heat of formation (Delta H-f(0)) for individual C60Sin clusters using a semiempirical molecular orbital method. For a small number of Si atoms (n < 3), it was found that each Si atom is preferentially bound to the 6/6 bonds (double bond between adjacent hexagon rings) of the C-60 substrate independently. On the other hand, for a large number of Si atoms (n greater than or equal to 3), besides the bond formation between Si atoms and the C-60, the adjacent Si atoms tend to form chemical bonds with each other. The n-dependence of Delta H-f(0) for the C60Sin was quantitatively interpreted by the number of Si atoms with dangling bonds in the framework of the isolated pentagon rule (IPR). It was revealed that the Si-Si bond formation is an essential process to successfully synthesize the C60Si60.

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  • Low-energy collision process of sodium cluster ions Reviewed

    H Tanaka, T Hanmura, S Nonose, T Kondow

    SIMILARITIES AND DIFFERENCES BETWEEN ATOMIC NUCLEI AND CLUSTERS   ( 416 )   193 - 199   1998

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    Dissociation dynamics of a size-selected sodium cluster ion, Na-9(+), in collision with a series of rare-gas atoms, He, Ne, Ar, Kr and Xe, was investigated by measuring the absolute cross sections by use of a tandem mass-spectrometer, The dominant processes for the dissociation are Na and Na-2 release from the parent cluster ion. Total cross sections for the dissociation except for the Xe collision is explained in a scheme of classical collision. In the Xe collision, it was found that the cross sections observed were smaller than the cross sections predicted by the classical collision scheme, probably because of long range interaction between the cluster ion and Xe atom. On the other hand, the branching fractions for the Na and the Na-2 release are predicted well by the orbital correlation diagrams for the dissociation systems.

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  • Collisional reactions of Na-n(+) (n=3-9) with N2O Reviewed

    H Tanaka, T Mizuno, F Ishizaki, S Nonose, T Kondow

    JOURNAL OF CHEMICAL PHYSICS   106 ( 10 )   4002 - 4007   1997.3

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    A collisional reaction of a sodium cluster ion, Na-n(+)(n=3-9), with a nitrous oxide molecule, N2O, was investigated by using a tandem mass-spectrometer equipped with four octopole ion guides. Two types of ions, NakO+ and Na-P(+) (p<n), were produced by the reaction; NakO+ and Na-p(+) result from oxidation and direct collisional dissociation of the parent cluster ion, Na-n(+), respectively. The absolute total cross section and partial cross sections for the NakO+ (oxidation) and Na-P(+) (direct dissociation) production were measured as a function of the collision energy of a given parent cluster ion, Na-n(+), in the energy range up to 5 eV (center-of-mass frame). The cross sections and their collision-energy dependence show that the oxidation proceeds when electron harpooning from Na-n(+) to N2O occurs and otherwise the direct collisional dissociation proceeds. (C) 1997 American Institute of Physics.

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  • Reaction dynamics of Na-n(+) in collision with molecular oxygen Reviewed

    S Nonose, H Tanaka, T Mizuno, F Ishizaki, T Kondow

    ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS   40 ( 1-4 )   75 - 77   1997

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    Reaction dynamics of sodium cluster ions, Na-n(+) (n = 2 - 9), in collision with molecular oxygen, O-2 was investigated by measuring the absolute dissociation cross sections and the branching fractions by using a tandem mass spectrometer equipped with several octapole ion guides. The mass spectrum of the product ions show that the dominant reaction channels are production of oxide ions, NakOi (i = 1,2), and intact ions, Na-p(+) (p < n). With increase in the collision energy, the cross section for the production of the oxide ions decreased, while that for the production of the intact ions increased. The collision-energy dependences of the cross section for the oxide formation reveals that electron harpooning from the molecule to Na-n(+), preludes the oxide-ion formation. On the other hand, the collision-energy dependences of the cross sections for the intact ion formation is explained by a hard-sphere-collision model similar to the collisional dissociation of Na-n(+) by rare-gas impact.

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  • Dissociation dynamics of Na-n(+) in collision with rare-gas atoms Reviewed

    S Nonose, H Tanaka, T Mizuno, NJ Kim, K Someda, T Kondow

    JOURNAL OF CHEMICAL PHYSICS   105 ( 20 )   9167 - 9174   1996.11

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    Dissociation dynamics of a sodium cluster ion, Na-n(+) (n=2-9 and 11), in collision with a rare gas atom (He or Ne) was investigated by measuring the absolute cross sections for the production of fragmented ions by using a tandem mass-spectrometer equipped with several octapole ion guides. The mass spectra of the fragmented ions show that release of Na and/or Na-2 from Na-n(+) occurs dominantly. The absolute total cross section for the dissociation of Na-n(+) and the absolute partial cross sections for the Na and/or the Na-2 release were determined at different collision energies and cluster sizes. The absolute total dissociation cross sections were calculated by a scheme that f dissociates with leaving Na and Na-2 unimolecularly, On the other hand, collisionally excited Na-n(+) the partial cross sections;for the Na and the Na-2 release were successfully explained by the orbital correlation diagram for the dissociation system; the dissociation channel involving an adiabatic transition was found to be influenced significantly by the collision energy and the cluster size. (C) 1996 American Institute of Physics.

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  • Electron harpooning in reactions of sodium cluster ions with nitrous oxide Reviewed

    H Tanaka, T Mizuno, S Nonose, T Kondow

    CHEMICAL PHYSICS LETTERS   253 ( 1-2 )   171 - 176   1996.4

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    The collisional reaction of Na-n(+) (2 less than or equal to n less than or equal to 9) with N2O was investigated by using a tandem mass spectrometer equipped with four octopole ion guides. Oxide ions, NakO+, and intact ions, Na-p(+) (p < n), were found to be produced from the reaction of Na-n(+) with N2O. The collision-energy dependence of the absolute cross section for each product channel was measured at collision energies up to 5 eV in the center-of-mass frame. The cross section for the production of NakO+ decreased with increasing collision energy, while that for the production of Na-p(+) increased. This observation is interpreted as that electron harpooning from Na-n(2) to N2O preludes NakO+ formation. The collision-energy dependence of the partial cross section for the production of Na-p(+) is explained by a hard sphere collision model employed in the explanation of the collisional dissociation of Na-n(2) by rare-gas impact.

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  • Role of electron pairing in collisional dissociation of Na-9(+) by a rare-gas atom Reviewed

    S Nonose, H Tanaka, T Mizuno, J Hirokawa, T Kondow

    JOURNAL OF CHEMICAL PHYSICS   104 ( 15 )   5869 - 5874   1996.4

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    A sodium cluster ion, Na-9(+), having a closed electronic shell was allowed to collide with a rare-gas atom (He or Ne), and collisionally fragmented ions were measured by using a tandem mass-spectrometer equipped with several octapole ion guides. The mass spectrum of the product ions show that sodium atom and dimer are released dominantly from the cluster ion, Na-9(+). The dependencies of the absolute cross sections for the Na and the Na-2 release on the collision energy were determined for collision energies up to 3 eV in the center of mass frame. The cross section for the Na-2 release increases much more rapidly than that for the Na release as the collision energy increases, while the cross sections for the Na and the Na-2 release start to rise at almost the same collision energy of 0.75 +/- 0.1 eV. The collision-energy dependencies are explained by orbital correlation diagrams for the Na-8(+) + Na and the Na-7(+) + Na-2 systems on the basis of a model that a spherical jellium of Na-9(+) is deformed by collision of a rare-gas atom. The total absolute cross sections are estimated by a two-step scheme: collisional excitation and dissociation. (C) 1996 American Institute of Physics.

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  • Dynamics on Dissociation of Sodium Cluster Ions by He Impact Reviewed

    H. Tanaka, T. Mizuno, J. Hirokawa, S. Nonose, T. Kondow

    Structures and Dynamics of Clusters   491 - 496   1996.3

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  • ナトリウムクラスターイオンの衝突過程とダイナミクス

    野々瀬真司, 田中秀樹, 水野智之, 廣川淳, 近藤保

    物性研究   65 ( 6 )   930 - 934   1996.3

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    Other Link: http://dl.ndl.go.jp/info:ndljp/pid/10938033

  • Collisional Reactions of Sodium Cluster Ion with Oxygen-Containing Molecules Reviewed

    S. Nonose, H. Tanaka, T. Mizuno, F. Ishizaki, T. Kondow

    Structures and Dynamics of Clusters   87 - 93   1996.3

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  • Collisional processes involving size-selected sodium-cluster ions Reviewed

    H Tanaka, T Mizuno, J Hirokawa, S Nonose, T Kondow

    SURFACE REVIEW AND LETTERS   3 ( 1 )   679 - 682   1996.2

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    Collision-induced reactions of Na-n(+) (n = 2-9) with Ne and Kr were investigated by means of a Tandem mass spectrometer equipped with octapole ion guide. The dominant processes were evaporation of a Na atom from Na-n(+) with even sizes or Na-2 molecules from those with odd sizes. The absolute cross section for the reaction was measured as functions of the parent-cluster size and the collision energy. The branching fractions of the daughter-ion production were also determined. These results are interpreted in a scheme of a pair interaction in jellium background.

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  • OBSERVATION THE XY(-) ABSTRACTION PRODUCTS IN THE REACTIONS X(-)+RY-]XY(-)+R - AN ALTERNATIVE TO THE S(N)2 MECHANISM AT SUPRATHERMAL COLLISION ENERGIES Reviewed

    DM CYR, MG SCARTON, KB WIBERG, MA JOHNSON, S NONOSE, J HIROKAWA, H TANAKA, T KONDOW, RA MORRIS, AA VIGGIANO

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   117 ( 6 )   1828 - 1832   1995.2

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    We report the formation of dihalide products from the endothermic gas-phase ion-molecule reaction of Cl- with CH3Br at suprathermal collision energies using both guided ion beam and selected ion flow drift tube (SIFDT) techniques. The cross sections for the Cl- + CH3Br reactions were determined using the guided ion beam apparatus over a center-of-mass collision energy range of 2-15 eV with the ClBr- product displaying a maximum near 7 eV. This result is found to be in good agreement (when convoluted with the appropriate velocity distribution) with the rate constant measured by the SIFDT. ICI- and I-2(-) are also found for the Cl- + CH3I and I- + RI reactions at elevated collision energies (less than or equal to 1.5 eV) in the SIFDT. The rates for halide displacement are found to be insensitive to collision energy. These results indicate that attack on the C-X bond may nor provide an efficient alternative to the S(N)2 mechanism for halide exchange in the asymmetric X(-) + CH3Y systems. This conclusion is supported by nb initio calculations (MP2LANL10Z level) which indicate that ClBr- can be formed by collinear attack at the halogen through a Cl...Br...CH3 intermediate.

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  • Collision Processes Involving Size-Selected Cluster Ions Reviewed

    S. Nonose, M. Ichihashi, H. Tanaka, T. Mizuno, J. Yamabe, T. Kondow

    Book of Abstracts 7th Intemational Symposium on Small Particles and Inorganic Clusters (ISSPIC7)   157   1994.9

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  • COLLISION-INDUCED REACTIONS OF (CH3OH)(N)H+ WITH RARE-GAS ATOMS Reviewed

    S NONOSE, H TANAKA, T NAGATA, T KONDOW

    JOURNAL OF PHYSICAL CHEMISTRY   98 ( 36 )   8866 - 8869   1994.9

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    Dissociation of protonated methanol cluster ions, (CH3OHH+ (n = 2-23), in collision with He, Ne, or Kr atoms were studied by means of a tandem mass spectrometer equipped with octapole ion guides. The mass spectra of the product ions show that the dominant process is evaporation of CH3OH molecules from (CH3-OHH+. The absolute cross section for the evaporation was measured as functions of the cluster sizes and the collision energy in the range 0.05-100 eV in the center of mass frame. The branching fractions for the product ions were also determined. It is inferred that the evaporation proceed via the collisional excitation and subsequent unimolecular dissociation.

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  • Collision-induced reactions of size-selected molecular clusterions Reviewed

    S. Nonose, M. Sakamoto, H. Tanaka, J. Hirokawa, M. Ichihashi, T. Kondow

    Book of Abstracts 6th Intemational Symposium on Small Particles and Inorganic Clusters (ISSPIC6)   26 ( 1-4 )   M - 081   1992.9

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  • COLLISION-INDUCED REACTIONS OF MOLECULAR CLUSTER IONS Reviewed

    S NONOSE, J HIROKAWA, M ICHIHASHI, M SAKAMOTO, T TAHARA, T KONDOW

    PHYSICS AND CHEMISTRY OF FINITE SYSTEMS : FROM CLUSTERS TO CRYSTALS, VOLS 1 AND 2   374   1125 - 1130   1992

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Books

  • 金属ナノ粒子の合成・設計・制御と応用技術 : 種々の合成法、サイズ・形状の制御と評価、分散・配合技術、応用展開

    宮川 雅矢, 田中 秀樹( Role: Contributor第2章 第7節 (5) 耐酸化性を含む多様な物性を有する銅ナノ粒子の合成と応用展開 pp.137-157)

    サイエンス&テクノロジー  2022.12  ( ISBN:9784864282482

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    Total pages:533 p, 図版 [25] p   Language:Japanese  

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  • 金属ナノ粒子、微粒子の合成、調製と最新応用技術

    宮川 雅矢, 田中 秀樹( Role: Contributor第1章 第4節 粘土を用いた銅ナノ粒子の合成と粒径,分散性制御)

    株式会社技術情報協会  2021.10  ( ISBN:9784861048623

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  • 「化学(全74ページ)」のうち「誰も教えてくれない!5スペクトルの基本,わかってる?(pp.25-30)」を監修

    宮川 雅矢, 監修, 田中 秀樹( Role: Supervisor (editorial))

    化学同人  2019.9 

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  • 「化学(全76ページ)」のうち「誰も教えてくれない!4スペクトルの基本,わかってる?(pp.20-25)」を監修

    宮川 雅矢, 監修, 田中 秀樹( Role: Supervisor (editorial))

    化学同人  2019.8 

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  • 「化学(全74ページ)」のうち「誰も教えてくれない!3スペクトルの基本,わかってる?(pp.36-40)」を監修

    宮川 雅矢, 監修, 田中 秀樹( Role: Supervisor (editorial))

    化学同人  2019.7 

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  • 「化学(全76ページ)」のうち「誰も教えてくれない!2スペクトルの基本,わかってる?(pp.54-57)」を監修

    宮川 雅矢, 監修, 田中 秀樹( Role: Supervisor (editorial))

    化学同人  2019.5 

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  • 「化学(全74ページ)」のうち「誰も教えてくれない!1スペクトルの基本,わかってる?(pp.21-24)」を監修

    宮川 雅矢, 監修, 田中 秀樹( Role: Supervisor (editorial))

    化学同人  2019.4 

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  • 「原子核とマイクロクラスター類似性と異質性(全94ページ)」のうち「ナトリウムクラスターイオンと含酸素分子との反応性衝突(pp.44-49)」を執筆

    編者, 阿部恭久他, 名 著者名, 田中秀樹, 野々瀬真司, 水野智之, 石崎史彦, 近藤保( Role: Sole author)

    京都大学基礎物理学研究所  1997.2 

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MISC

  • 銀三角形ナノプレートの合成および置換反応による不斉光学特性の発現

    田中 秀樹

    ナノスケール・ミクロスケールから見えるビックな世界   2013.10

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  • Report on the European Aerosol Conference 2009

    Hideki Tanaka, Yasuo Morimoto

    Earozoru Kenkyu   24 ( 4 )   290 - 293   2009.12

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  • ナノ半田を用いた金属ナノ粒子のナノネットワーク構造形成

    田中秀樹

    化学   59 ( 8 )   63 - 64   2004.8

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  • Structures and reactions of biomolecular ions produced with electrospray ionization

    S Nonose, S Iwaoka, H Tanaka, N Okai, T Shibakusa, K Fuke

    EUROPEAN PHYSICAL JOURNAL D   24 ( 1-3 )   335 - 338   2003.6

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    Photo-induced reaction of [Fe(III)-protoporphyrin](+) (hemin(+)) ions solvated with dimethylsulfoxide (DMSO) is investigated by using a tandem mass spectrometer with electrospray ionization. We measure the photodissociation yields of mass-selected hemin(+()DMSO)(n) clusters for n = 0-3. The mass spectra of the fragment ions show the beta-cleavage of carboxymethyl groups in addition to the evaporation of solvent molecules. Yield of the beta-cleavage reaction is found to depend strongly on the excitation energv and the number of solvent molecules. We also examine photo-induced reactions of multiply-charged cytochrome c ions, (M + nH)(n+) (n = 9-17). Photoionization is found to be the dominant process for the lower charged states (n = 9-12) and its yield decreases rapidly with increasing the charge. The photoionization is ascribed to the emission of electron by multiphoton excitation of heme under the influence of Coulomb attractive potential arising from the charges in the polypeptide chain. Model calculations of the Coulomb potential suggest that the structure of the polypeptide chain is completely elongated.

    DOI: 10.1140/epjd/e2003-00168-7

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  • Collisional Processes of Cluster Ions.

    NONOSE SHINJI, HIROKAWA JUN, ICHIHASHI MASAHIKO, TANAKA HIDEKI, NAGATA TAKESHI, KONDO TAMOTSU

    化学反応討論会講演要旨集   10th   121 - 122   1994.5

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  • Collisional Reaction Process of Sodium Cluster Ions.

    TANAKA HIDEKI, HIROKAWA JUN, NONOSE SHINJI, KONDO TAMOTSU

    化学反応討論会講演要旨集   10th   119 - 120   1994.5

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  • クラスターイオンの衝突誘起解離反応

    広川淳, 市橋正彦, 田中秀樹, 野々瀬真司, 永田敬, 近藤保

    化学反応討論会講演要旨集   9th   45 - 46   1993.6

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  • サイズを選択したメタノールクラスターイオンの衝突誘起過程

    田中秀樹, 野々瀬真司, 永田敬, 近藤保

    日本化学会講演予稿集   65th ( 1 )   270   1993.3

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    J-GLOBAL

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  • 分子クラスターイオンの衝突誘起反応

    坂本将俊, 田中秀樹, 野々瀬真司, 近藤保

    分子構造総合討論会講演要旨集   1992   456   1992.9

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Presentations

  • Annealing Effect on Graphene/Copper Nanoparticle Composite Materials for Thermoelectric Conversion Application

    Weili Liao, Kouki Saito, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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    Language:Japanese   Presentation type:Oral presentation (general)  

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  • Dependence of thermoelectric performance of PEDOT:PSS/Graphene multilayer thin films on the amounts of Graphene

    Keito Uchida, Yuma Watanabe, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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  • Thermoelectric properties of Ag2Se nanowires /BBL:PEI composite films and their composition dependence

    Haruna Kasugai, Syunichiro Miwa, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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  • Improvement of thermoelectric properties of α-Cu2Se nanowires by annealing

    Yusuke Morikawa, Kazuki Munakata, Insoo Kang, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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  • Oxidation reaction for alcohols catalyzed by copper nanoparticle-titanium dioxide composites and its substituent dependence

    Chiharu Mimura, Masahiro Suzuki, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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  • Synthesis of copper nanoparticles/PNIPAM composite material using photoreduction method and evaluation of thermal responsiveness

    Itsuki Yamagishi, Takuma Okabe, Shunya Sakane, Hideki Tanaka

    The 104th CSJ Annual Meeting (2024)  2024.3 

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  • Synthesis of copper nanoparticles/thermo-responsive polymers and their photo-induced thermal response

    Itsuki Yamagishi, Takuma Okabe, Shunya Sakane, Hideki Tanaka

    MRM2023/IUMRS-ICA2023  2023.11 

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    Event date: 2023.11    

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  • Thermoelectric performance enhancement of PEDOT:PSS/Graphene multilayer thin films with intermolecular interactions

    Keito Uchida, Takashi Shimizu, Koki Saito, Shunya Sakane, Hideki Tanaka

    MRM2023/IUMRS-ICA2023  2023.11 

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  • Fabrication of n-type composite thin films of inorganic nanowires/conductive polymers and their thermoelectric properties

    Haruna Kasugai, Shunichiro Miwa, Shunya Sakane, Hideki Tanaka

    MRM2023/IUMRS-ICA2023  2023.11 

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    Event date: 2023.11    

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  • Vacancy control in Cu2Se nanowires and their thermoelectric properties

    Shunya Sakane, Kazuki Munakata, Yusuke Morikawa, Haruhiko Udono, Hideki Tanaka

    MRM2023/IUMRS-ICA2023  2023.11 

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  • TiO2ナノ粒子表面電子ドーピングが及ぼすPEDOT:PSSの熱電特性への影響

    TSJ2023  2023.9 

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  • 欠陥制御したCu2Seナノワイヤ;グラフェン複合薄膜の熱電物性評価

    TSJ2023  2023.9 

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  • Cu2Seナノワイヤの熱電物性におけるキャリア輸送特性のCu空孔依存性

    2023.9 

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  • Protectant-free degradative Cu nanoparticles and their catalytic application

    Hideki Tanaka, Jun Hirokawa

    EAC2023  2023.9 

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  • Thermoelectric performance of PEDOT:PSS/graphene multilayer thin films enhanced by intermolecular interactions

    Keito Uchida, Takashi Shimizu, Koki Saito, Shunya Sakane, Hideki Tanaka

    The 39th International Conference on Thermoelectrics (ICT2023)  2023.6 

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  • Thermoelectric properties of crystal structure-controlled copper selenide nanowires

    Yusuke Morikawa, Kazuki Munakata, Tatsuki Miura, Shunya Sakane, Hideki Tanaka

    The 39th International Conference on Thermoelectrics (ICT2023)  2023.6 

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  • Thermoelectric properties of n-type conductive polymers hybridized with Ag2Se nanowires

    Shunya Sakane, Shunichiro Miwa, Haruna Kasugai, Hideki Tanaka

    The 39th International Conference on Thermoelectrics (ICT2023)  2023.6 

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  • Synthesis of copper nanoparticles/thermo-responsive polymers and photo-induced thermal response

    Itsuki Yamagishi, Shunya Sakane, Hideki tanaka

    2023.5 

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  • 光還元法によるセレン化銅ナノワイヤの創製と熱電応用への展開

    2023.5 

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  • Molecular shape selectivity of catalytic activity of copper nanoparticles using pores of zeolite

    Harunobu Iwastuki, Kenta Takaoka, Shunya Sakane, Hideki Tanaka

    The 103rd CSJ Annual Meeting (2023)  2023.3 

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  • Synthetic mechanism of a-Cu2Se nanowires by photoreduction method

    Tatsuki Miura, Kazuki Munakata, Yusuke Morikawa, Shunya Sakane, Kazu Okumura, Hideki Tanaka

    The 103rd CSJ Annual Meeting (2023)  2023.3 

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  • Improvement of Thermoelectric Properties of PEDOT:PSS and Titanium Dioxide Composite Thin Films

    Takuto Toyama, Shunya Sakane, Hideki Tanaka

    The 103rd CSJ Annual Meeting (2023)  2023.3 

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  • Evaluate chemical structure of Graphene/Cu nanoparticles and their thermoelectric properties

    Koki Saito, Shimizu Takashi, Shunya Sakane, Hideki Tanaka

    The 103rd CSJ Annual Meeting (2023)  2023.3 

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  • Synthesis of Cu2+xSe nanowires and their thermoelectric properties

    Kazuki Munakata, Tatsuki Miura, Yusuke Morikawa, Shunya Sakane, Hideki Tanaka

    The 103rd CSJ Annual Meeting (2023)  2023.3 

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  • Thermoelectric Power Factor Enhancement of PEDOT:PSS by Formation of Cu2Se Nanowire Network Structures

    Shunya Sakane, Shunichiro Miwa, Tatsuki Miura, Kazuki Munakata, Takafumi Ishibe, Yoshiaki Nakamura, Hideki Tanaka

    2022 MRS Fall Meeting & Exhibit  2022.12 

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    Event date: 2022.11 - 2022.12

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  • Synthesis of Graphene/Cu Nanoparticles by Photoreduction Method for Enhancing Thermoelectric Power Factor

    Koki Saito, Takashi Shimizu, Shunya Sakane, Hideki Tanaka

    2022 MRS Fall Meeting & Exhibit  2022.11 

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    Event date: 2022.11 - 2022.12

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  • Synthesis of single phase a-Cu2Se nanowires by photoreduction method for thermoelectric applications

    Tatsuki Miura, Kazuki Munakata, Shunichiro Miwa, Shunya Sakane, Hideki Tanaka

    2022 MRS Fall Meeting & Exhibit  2022.11 

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    Event date: 2022.11 - 2022.12

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  • Thermoelectric properties of Cu2Se nanowires/PEDOT:PSS composite thin films

    S. Sakane, S. Miwa, T. Miura, K. Munakata, T. Ishibe, Y. Nakamura, H. Tanaka

    ICOT2022 (International Conference on Organic and Hybrid Thermoelectrics)  2022.10 

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  • Thermoresponsive behavior induced by plasmonic heating of copper nanoparticles

    Sunya Sakane, Toshiki Anji, Itsuki Yamagishi, Issei Kohara, Hideki Tanaka

    The 16th Annual Meeting of Japan Society for Molecular Science  2022.9 

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  • Catalytic activity of copper nanoparticles formed in pores of zeolite for alcohol oxidation

    Harunobu Iwatsuki, Kenta Takaoka, Hukashi Iguchi, Shunya Sakane, Hideki Tanaka

    The 16th Annual Meeting of Japan Society for Molecular Science  2022.9 

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  • Synthesis of a-Cu2Se nanowires by photoreduction method and their electronic structures

    Tatsuki Miura, Kazuki Munakata, Shunichiro Miwa, Shunya Sakane, Hideki Tanaka

    The 16th Annual Meeting of Japan Society for Molecular Science  2022.9 

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  • Fabrication of graphene-inserted PEDOT:PSS thin films and their thermoelectric properties

    TSJ2022  2022.8 

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  • Synthesis of Graphene/Cu nanoparticles by photoreduction method and their thermoelectric properties

    TSJ2022  2022.8 

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  • PEDOT:PSS に導入したCu2Seナノワイヤの熱電出力因子に与える影響

    坂根 駿也, 三輪 俊一朗, 石部 貴史, 中村 芳明, 田中 秀樹

    第19回日本熱電学会学術講演会 (TSJ2022)  2022.8 

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  • Synthesis of Cu nanostructures by photocatalysis and their application to thermoelectric materials

    Akito Ayukawa, Takuto Toyama, Syunya Sakane, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Thermoelectric performance enhancement of PEDOT:PSS by introduction of copper selenide nanowires

    Shunichiro Miwa, Tatsuki Miura, Kazuki Munakata, Syunya Sakane, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Thermoelectric property enhancement of graphene-inserted PEDOT:PSS thin films

    Takashi Shimizu, Koki Saito, Syunya Sakane, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Thermoresponsive behavior of copper nanoparticles/pNIPAM composites induced by localized surface plasmon resonance

    Shunya Sakane, Toshiki Anji, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Synthesis of Cu nanoparticles/titanium oxide composites and their catalytic activities for benzyl alcohol oxidation

    Masahiro Suzuki, Yuma Watanabe, Syunya Sakane, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Synthesis of alloy nanoparticles by galvanic replacement reaction using copper nanoparticle-zeolite composite

    Kenta Takaoka, Harunobu Iwatsuki, Syunya Sakane, Hideki Tanaka

    The 102nd CSJ Annual Meeting  ( Online Meeting )   2022.3  The Chemical Society of Japan

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  • Novel strategy for highly-catalytic Cu nanoparticles realized in cotton-candy-like nanosheets assembly International conference

    Hitomi Kotake, Masaya Miyagawa, Hideki Tanaka

    Pacifichem 2021  ( Online Meeting )   2021.12 

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  • 光還元法によるCu NP/TiO2の合成と熱電応用に向けた導電性高分子PEDOT:PSSとの複合薄膜化

    鮎川 瞭仁, 東山 拓社, 森本 啓幹, 坂根 駿也, 田中 秀樹

    第11回化学フェスタ2021  ( Online Meeting )   2021.10  The Chemical Society of Japan

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  • Cuナノ粒子を光触媒とした還元型分解反応

    小竹 ひとみ, 坂根 駿也, 田中 秀樹

    第11回化学フェスタ2021  ( Online Meeting )   2021.10  The Chemical Society of Japan

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  • スピンコート法により作製したPEDOT:PSS/Graphene積層薄膜の熱電特性評価

    清水 隆司, 坂根 駿也, 田中 秀樹

    第18回 日本熱電学会学術講演会  ( Online Meeting )   2021.8  Thermoelectrics Society of Japan

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  • 光還元法によるCu2Seナノワイヤの合成とPEDOT:PSSとの複合薄膜化

    三輪 俊一朗, 坂根 駿也, 田中 秀樹

    第18回 日本熱電学会学術講演会  ( Online Meeting )   2021.8  Thermoelectrics Society of Japan

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  • Aerobic oxidation for benzyl alcohol by Cu nanoparticle−zeolite nanocomposites as catalysts

    Wakaba Yamamoto, Kai Akimoito, Shunya Sakane, Hideki Tanaka

    The 101st CSJ Annual Meeting  ( Online Meeting )   2021.3  The Chemical Society of Japan

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  • Relation between photocatalystic activity of nanosheets-supported Cu nanoparticles and their assembly state

    Hitomi Kotake, Masaya Miyagawa, Hideki Tanaka

    The 101st CSJ Annual Meeting  ( Online Meeting )   2021.3  The Chemical Society of Japan

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  • The effect of Cu nanoparticles in pores of zeolite on catalytic activities

    Shunya Sakane, Kai Akimoto, Kishin Konishi, Hideki Tanaka

    The 101st CSJ Annual Meeting  ( Online Meeting )   2021.3  The Chemical Society of Japan

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  • Synthesis of copper nanoparticles with thermoresponsive polymer as a protectant by photoreduction

    Toshiki Anji, Kai Akimoto, Syunya Sakane, Hideki Tanaka

    The 101st CSJ Annual Meeting  ( Online Meeting )   2021.3  The Chemical Society of Japan

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  • Difference in activity of copper nanoparticles supported on nanosheets depending on the reaction field

    Hitomi Kotake, Masaya Miyagawa, Hideki Tanaka

    The 18th Annual Meeting of Society of Nano Science and Technology  ( Yokohama )   2020.5  The Society of Nano Science and Technology

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  • Copper nanocubes synthesized directly on nanosheet functionalized by azobenzenethiol with deposition-desorption method

    Yoshiki Nishiyama, Masaya Miyagawa, Hideki Tanaka

    The 100th CSJ Annual Meeting  ( Chiba )   2020.3  The Chemical Society of Japan

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  • Production of copper nanoparticles with zeolite by photoreduction and their catalytic activities

    Kai Akimoto, Kazu Okumura, Hideki Tanaka

    The 100th CSJ Annual Meeting  ( Chiba )   2020.3  The Chemical Society of Japan

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  • Surface modification of diameter-controlled Cu nanoparticles with thiol by desorption from suppor

    Yuya Sakaguchi, Masaya Miyagawa, Hideki Tanaka

    The 100th CSJ Annual Meeting  ( Chiba )   2020.3  The Chemical Society of Japan

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  • Significance in hierarchy of Cu nanoparticles on nanosheet for functionalization

    MIYAGAWA, Masaya, KOTAKE, Hitomi, NISHIO, Kengo, HIGASHI, Kohei, TANAKA, Hideki

    The 100th CSJ Annual Meeting  ( Chiba )   2020.3  The Chemical Society of Japan

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  • Plasmonic photoluminescence of dispersive Cu nanoparticles: Significance in nanostructure and energy transfer system

    Masaya Miyagawa, Kengo Nishio, Yoshiki Nishiyama, Hideki Tanaka

    第13回分子科学討論会2019  ( Nagoya )   2019.9  Japan Society for Molecular Science

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  • 固体反応場を模倣したナノシート集合体中における銅ナノ粒子のプラズモン発光

    西尾謙吾, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第9回サマーセミナー2019  ( Kochi )   2019.9  The Chemical Society of Japan

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  • サポナイト上から脱着した銅ナノキューブに修飾したアゾベンゼンチオラートの光物性

    西山誉志貴, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第9回サマーセミナー2019  ( Kochi )   2019.9  The Chemical Society of Japan

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  • 銅ナノ粒子を担持したナノシート複合体の光誘起電子移動

    小竹ひとみ, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第9回サマーセミナー2019  ( Kochi )   2019.9  The Chemical Society of Japan

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  • 銅ナノ粒子を担持したナノシートへのピレンの吸着および光照射時の蛍光スペクトル変化

    安治敏輝, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第9回サマーセミナー2019  ( Kochi )   2019.9  The Chemical Society of Japan

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  • サポナイト上の銅ナノ粒子を触媒としたUV-vis 分光法によるニトロフェノールの還元反応の解析

    山本若葉, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第9回サマーセミナー2019  ( Kochi )   2019.9  The Chemical Society of Japan

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  • 固体を模倣した光反応場としてのナノシート集合体内における銅ナノ粒子発光

    西尾 謙吾, 宮川 雅矢, 田中 秀樹

    第63回粘土科学討論会(2019)  ( Saitama )   2019.9  The Clay Science Society of Japan

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  • 銅ナノ粒子をマーカーとしたナノシートの集合状態の可視化と光触媒活性との関係

    小竹 ひとみ, 西尾 謙吾, 宮川 雅矢, 田中 秀樹

    第63回粘土科学討論会(2019)  ( Saitama )   2019.9  The Clay Science Society of Japan

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  • サポナイト上に合成した銅ナノキューブの脱着及びアゾベンゼン類縁体による修飾

    西山 誉志貴, 宮川 雅矢, 田中 秀樹

    第63回粘土科学討論会(2019)  ( Saitama )   2019.9  The Clay Science Society of Japan

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  • 銅ナノ粒子のサポナイトからの脱着率とチオールによる保護との関係

    坂口 侑矢, 宮川 雅矢, 田中 秀樹

    第63回粘土科学討論会(2019)  ( Saitama )   2019.9  The Clay Science Society of Japan

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  • サポナイトナノシート上に合成した銅ナノ粒子の白金族元素による合金化

    宮川 雅矢, 西尾 謙吾, 東 耕平, 笹島 康平, 田中 秀樹

    第63回粘土科学討論会(2019)  ( Saitama )   2019.9  The Clay Science Society of Japan

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  • Affection of Gas-Born Metal Nanoparticles on DNA Structure International conference

    Hideki Tanaka

    EAC2019  2019.8 

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  • Introduction of hierarchical structure for enhanced photocatalytic activity of Cu nanoparticles hybridized with saponite nanosheets International conference

    Masaya Miyagawa, Akane Shibusawa, Kengo Nishio, Hideki Tanaka

    International Conference on Clay Science and Technology (EUROCLAY 2019)  ( France, Paris )   2019.7 

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  • Photoluminescent Cu nanoparticles induced by energy transfer on saponite nanosheets International conference

    Kengo Nishio, Masaya Miyagawa, Hideki Tanaka

    International Conference on Clay Science and Technology (EUROCLAY 2019)  ( France, Paris )   2019.7 

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  • Origin of Gas-liquid Interface Change in Synthesis of Cu Nanoparticles by Photocatalyst

    Ryoya Seki, Masaya Miyagawa, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • Synthesis of copper nanoplates by photoreduction on saponite using copper nitrate

    Yuya Yamazaki, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • Synthesis of copper nanoparticles by photoreaction for thin film blended of copper acetate with montmorillonite

    Kai Akimoto, Akane Shibusawa, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • Photocatalytic activity of Cu nanoparticles directly synthesized on nanosheets and effect of hierarchical structure of nanocomposite

    Masaya Miyagawa, Akane Shibusawa, Kengo Nishio, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • Application of oxidation-resistive Cu nanoparticles for epoxidation

    Kota Yoneyama, Masaya Miyagawa, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • Photoluminescence of copper nanoparticle by constructing energy transfer system on nanosheet and effect of surface plasmon resonance

    Kengo Nishio, Masaya Miyagawa, Hideki Tanaka

    The 99th CSJ Annual Meeting  ( Kobe )   2019.3  The Chemical Society of Japan

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  • サポナイト上で粒径制御された銅ナノ粒子:合成法の確立と電子ドナーとしての利用

    澁澤朱音, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第8回サマーセミナー2018  ( Tsukuba )   2018.9  The Chemical Society of Japan

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  • オレフィンを原料とした銅ナノ粒子カオリナイト複合体の触媒活性評価

    米山浩太, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第8回サマーセミナー2018  ( Tsukuba )   2018.9  The Chemical Society of Japan

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  • サポナイト上でのエネルギー移動を利用した銅ナノ粒子の発光現象

    西尾謙吾, 宮川雅矢, 田中秀樹

    低次元系光機能材料研究会第8回サマーセミナー2018  ( Tsukuba )   2018.9  The Chemical Society of Japan

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  • Morphological control of Cu nanoparticles by counter anion

    Masaya Miyagawa, Akane Shibusawa, Yoshiki Nishiyama, Hideki Tanaka

    第12回分子科学討論会2018  ( Fukioka )   2018.9  Japan Society for Molecular Science

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  • 粘土上でモルフォロジー制御された銅ナノ粒子合成法の確立と保護剤フリーを活かした機能化

    宮川雅矢, 澁澤朱音, 西尾謙吾, 田中秀樹

    第62回粘土科学討論会(2018)  ( Tokyo )   2018.9  The Clay Science Society of Japan

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  • サポナイトを光反応場とした銅ナノ粒子の発光現象

    西尾謙吾, 宮川雅矢, 田中秀樹

    第62回粘土科学討論会(2018)  ( Tokyo )   2018.9  The Clay Science Society of Japan

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  • Plasmonic photoluminescence realized by using protectant-free Cu nanoparticle with acridine orange International conference

    K. Nishio, M. Miyagawa, H. Tanaka

    ISSPIC19  ( China, Hangzhou )   2018.8 

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  • Size and Shape Controls of Protectant-free Cu Nanoparticles by Counter Anions International conference

    M. Miyagawa, A. Shibusawa, M. Usui, Y. Imura, H. Tanaka

    ISSPIC19  ( China, Hangzhou )   2018.8 

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  • Synthesis Mechanism of Oxide-free Cu Nanoparticles under Air International conference

    R. Seki, M. Miyagawa, H. Tanaka

    ISSPIC19  ( China, Hangzhou )   2018.8 

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  • Environmental-friendly synthesis of oxide-free Cu nanoparticles with high oxidation resistance and their XAFS analysis International conference

    Hideki Tanaka, Masaya Miyagawa, Kazu Okumura

    XAFS17  ( Poland, Krakow )   2018.7 

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  • 吸着媒上での銅ナノ粒子-アクリジンオレンジ複合体の形成とプラズモン発光の発現

    西尾謙吾, 宮川雅矢, 田中秀樹

    ナノ学会第16大会  ( 東京 )   2018.5  The Society of Nano Science and Technology

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  • 酸素促進型の銅ナノ粒子合成における反応中間体の検証

    関椋也, 宮川雅矢, 田中秀樹

    ナノ学会第16大会  ( 東京 )   2018.5  The Society of Nano Science and Technology

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  • 保護剤フリーな銅ナノキューブの合成とアゾベンゼンによる光機能化

    宮川雅矢, 井村悠, 臼井美晴, 田中秀樹

    ナノ学会第16大会  ( 東京 )   2018.5  The Society of Nano Science and Technology

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  • Photodegradation of methylviologen by plasmon excitation of protectant-free Cu nanoparticle

    Akane Shibusawa, Masaya Miyagawa, Hideki Tanaka

    日本化学会第98春季年会(2018)  2018.3 

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  • Photoluminescence of Cu nanoparticles by using adsorption of acridine orange on clay

    Kengo Nishio, Akane Shibusawa, Masaya Miyagawa, Hideki Tanaka

    日本化学会第98春季年会(2018)  2018.3 

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  • Synthesis of oxide-free Cu nanoparticles and oxygen facilitation property

    Ryoya Seki, Yuhei Nakamura, Masaya Miyagawa, Hideki Tanaka

    日本化学会第98春季年会(2018)  2018.3 

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  • Morphological control of protectant-free Cu nanoparticles supported on clay

    Masaya Miyagawa, Akane Shibusawa, Miharu Usui, Yu Imura, Hideki Tanaka

    日本化学会第98春季年会(2018)  2018.3 

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  • Synthesis of oxide-free Cu nanoparticles under the atmospheric condition and their complete decomposition

    Hideki Tanaka

    EMN Meeting on Droplets 2017  2017.12 

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  • Diameter and dispersibility controls of Cu nanoparticles by microscopic aggregation of clay

    Masaya Miyagawa, Akane Shibusawa, Kengo Nishio, Hideki Tanaka

    分子科学討論会2017  2017.9 

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  • サポナイトを吸着媒とした蛍光色素による銅ナノ粒子の発光特性の発現

    宮川雅矢, 西尾謙吾, 澁澤朱音, 田中秀樹

    粘土科学討論会2017  2017.9 

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  • Catalytic reaction of reproducible oxide-free copper nanoparticles with gaseous oxides

    Hideki Tanaka, Masaya Miyagawa, Jun Hirokawa

    EAC2017  2017.8 

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  • Morphology, reactivity and dispersibility controls of copper nanoparticles with layered clay minerals

    Masaya Miyagawa, Akane Shibusawa, Hideki Tanaka

    ICC2017 (16th International Clay Conference)  2017.7 

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  • Syntheses of copper nanoparticles and triangular nanoplates with saponite by photoreduction

    Akane Shibusawa, Masaya Miyagawa, Kaho Maeda, Hideki Tanaka

    ICC2017 (16th International Clay Conference)  2017.7 

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  • Synthesis of Copper Nanoparticle with Controlled Diameter in Clay Mineral Dispersion

    Akane Shibusawa, Masaya Miyagawa, Hideki Tanaka

    日本化学会第97春季年会(2017)  2017.3 

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  • Formation and decomposition mechanisms of lustrous copper nanoparticle film and its electric conductivity

    Masaya Miyagawa, Mari Yonemura, Kazuki Ohno, Hideki Tanaka

    日本化学会第97春季年会(2017)  2017.3 

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  • Reactivity and structual change of protectant-substituted Ag nanoplates with DNAs

    S. Takemoto, K. Iwai, H. Nanjo, M. Miyagawa, H. Tanaka

    EAC2016  2016.9 

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  • Synthesis of copper nanoparticles adsorbed on layered clay minerals without capping agents

    Masaya Miyagawa, Akane Shibusawa, Kaho Maeda, Hideki Tanaka

    The 10th Annual meeting of Japan Society for Molecular Science  2016.9 

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  • サポナイト上に合成した銅ナノ粒子の酸化特性と光学的特性

    宮川雅矢, 澁澤朱音, 小澤美優, 前田夏穂, 田中秀樹

    粘土科学討論会2016  2016.9 

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  • Synthesis of air-stable Cu nanoparticles and their decomposition with air-exposure

    T. Aoki, Y. Akiyama, M. Miyagawa, H. Tanaka

    ISSPIC18  2016.8 

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  • Highly air-stable Cu nanodisks on a layered clay mineral and their production mechanism

    M. Miyagawa, T. Aoki, H. Tanaka

    ISSPIC18  2016.8 

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  • Eco-friendly synthesis of copper nanoparticles with oxidation-free and regenerative properties

    Hideki Tanaka

    EMN Meeting on Droplets 2016  2016.5 

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  • 銅ナノ粒子の耐酸化性付与技術と今後の課題

    田中 秀樹

    アンドテック講演会  2016.3 

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  • Production and reactivity of oxidation-resistant metallic nanoparticles on carbon nanotubes

    Hideki Tanaka

    EMN Meeting on Carbon Nanostructures  2016.3 

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  • Synthesis and optical response of Ag triangular nanoplates protected by photochromic molecules

    IWAI, Ken, TAKEMOTO, Syuji, MIYAGAWA, Masaya, TANAKA, Hideki

    日本化学会第96春季年会  2016.3 

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  • Synthesis of Cu nanodisks adsorbed on a layered clay mineral

    MIYAGAWA, Masaya, YONEMURA, Mari, MAEDA, Toshiki, TOKUDA, Ryo, TANAKA Hideki

    日本化学会第96春季年会  2016.3 

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  • Synthesis and kinetic analysis of Cu nanoparticles by photocatalytic activity of TiO2

    AOKI, Takuya, YONEMURA, Mari, MIYAGAWA, Masaya, TANAKA, Hideki

    日本化学会第96春季年会  2016.3 

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  • Chemical Response of Metal Nanoparticles Synthesized by Environment-friendly Method

    Hideki Tanaka

    EMN Bangkok Meeting 2015  2015.11 

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  • カオリナイト層間を利用した銅ナノ粒子の光による合成とその生成機構

    宮川雅矢, 米村茉莉, 前田利輝, 徳田諒, 田中秀樹

    第59回粘土科学討論会  2015.9 

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  • Formation mechanism of Cu nanoparticles synthesized by photoreduction method

    T. Aoki, M. Yonemura, H. Tanaka

    EAC2015  2015.9 

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  • Synthesis and optical response of Ag triangular nanoplates protected by photochromic azobenzene

    K. Iwai, H. Nanjyo, N. Kinoshita, N. Nishida, H. Tanaka

    EAC2015  2015.9 

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  • カオリナイト層間で生成させた銅ナノ粒子の酸素耐性および可逆的特性

    米村茉莉, 宮川雅矢, 前田利輝, 徳田諒, 田中秀樹

    第59回粘土科学討論会  2015.9 

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  • In situ observation of reproducible copper nanoparticles

    Hideki Tanaka, Takuya Aoki, Naoki Nishida, Kazu Okumura

    XAFS16  2015.8 

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  • Metal Nanoparticles Adhesion to Biomolecules through Gas-Liquid Interface

    Hideki Tanaka

    EMN Meeting on Droplets 2015  2015.5 

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  • 気相生成銀ナノ粒子の液相分散生体分子に対する影響とその粒径依存性

    田中 秀樹

    粉体工学会春季研究発表会2015  2015.5 

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  • Synthesis and structural analysis of metallic nanocolloid by photoreduction with photosensitizer

    NANJYO, Hiroki, IWAI,Ken, KINOSHITA, Naoya, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第95春季年会  2015.3 

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  • Collection of metal nanoparticles on the electrode and its application to photocatalytic reaction

    YONEMURA, Mari, AOKI, Takuya, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第95春季年会  2015.3 

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  • Size-dependent analysis of gas-born Ag nanoparticles introduced into DNA dispersion

    Hideki Tanaka

    2nd KANOMAX Aerosol Workshop  2015.3 

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  • Regenerative synthesis of copper nanoparticles on TiO2 nanoparticles by photoreduction

    Naoki Nishida, Takuya Aoki, Hideki Tanaka

    ISSPIC17  2014.9 

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  • Enhancement of photocatalytic activity of TiO2 nanoparticles by addition of Ag nanoparticles

    Mari Yonemura, Naoki Nishida, Hideki Tanaka

    ISSPIC17  2014.9 

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  • Formation and structural analysis of composite of Ag nanoplates with TiO2 nanoparticles

    Hiroki Nanjyo, Ken Iwai, Naoya Kinoshita, Naoki Nishida, Hideki Tanaka

    ISSPIC17  2014.9 

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  • Regenerative synthesis of copper nanoparticles by photoreduction and their catalytic activity

    Hideki Tanaka, Takuya Aoki, Naoki Nishida

    分子科学討論会2014  2014.9 

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  • 気相生成ナノ粒子の液相への導入とそのサイズ依存性

    田中 秀樹

    第3回イオン移動度研究会  2014.4 

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  • 銀三角形ナノプレート上へのキラルチオール分子の導入およびその不斉光学特性に関する研究

    木下 直哉, 伊藤 太平, 西田 直樹, 田中 秀樹

    日本化学会第94春季年会  2014.3 

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  • Size dependent observation for interaction of gas-born Ag nanoparticles with DNA dispersion

    SHIBATA, Mina, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第94春季年会  2014.3 

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  • Regenerative synthesis of copper nanoparticles formed on titanium oxide nanoparticles and their catalytic activity

    NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第94春季年会  2014.3 

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  • Chiral Ag triangular nanoplate synthesized by protectant-substitution reaction

    Naoki Nishida, Yasuhiro Kojima, Hideki Tanaka

    第7回分子科学討論会  2013.9 

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  • Synthesis of Ag triangular nanoplates protected by glutathione and their interaction of hemoglobin

    N. Kinoshita, T. Ito, N. Nishida, H. Tanaka

    EAC2013  2013.9 

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  • Interaction of gas-born Ag nanoparticles with DNAs of salmon testes

    M. Shibata, N. Nishida, H. Tanaka

    EAC2013  2013.9 

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  • Chiral D-/L-Penicillamine-protected Ag Triangular Nanoplates Synthesized by Substitution Reaction

    Naoki Nishida, Yasuhiro Kojima, Hideki Tanaka

    TNT2013  2013.9 

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  • 銀三角形ナノプレートによるλDNAの高次構造変化に関する研究

    伊藤太平, 西田直樹, 田中秀樹

    日本化学会春季年会  2013.3 

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  • 表面プラズモンに誘起された三角形ナノプレートの不斉光学特性に関する研究

    西田直樹, 小島康裕, 田中秀樹

    日本化学会春季年会  2013.3 

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  • Synthesis of copper nanoparticles formed on carbon nanotubes by photochemical process

    N. Nishida, A. Miyashita, H. Tanaka

    EAC2012  2012.9 

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  • Structure deformation of Ag nanoparticle clusters induced by deposition onto carbon nanotubes

    T. Shinohara, N. Nishida, H. Tanaka

    EAC2012  2012.9 

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  • Synthesis of Ag triangular nanoplates protected by glutathione and their interaction of λDNA sequence

    T. Ito, Y. Kojima, N. Nishida, H. Tanaka

    ISSPIC16  2012.7 

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  • Synthesis and chrpotical analysis of chiral Ag triangular nanoplates protected by penicillamine

    Y. Kojima, N. Nishida, H. Tanaka

    ISSPIC16  2012.7 

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  • Structure analysis of size-selected Ag nanoparticle clusters

    T. Shinohara, N. Nishida, H. Tanaka

    日本化学会第92春季年会  2012.3 

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  • Melting process of diameter-selected Ag nanoparticle produced in gas phase

    D. Sugiura, N. Nishida, H. Tanaka

    日本化学会第92春季年会  2012.3 

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  • Synthesis of chiral Ag triangular nanoplates and their chiroptical property

    Y. Kojima, N. Nishida, H. Tanaka

    日本化学会第92春季年会  2012.3 

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  • Synthesis of copper nanoparticles formed on carbon nanotubes by photo irradiation

    N. Nishida, A. Miyashita, H. Tanaka

    日本化学会第92春季年会  2012.3 

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  • Synthesis of Ag:SG triangular nanoplates and their interection of λ DNA sequence

    T. Ito, Y. Kojima, N. Nishida, H. Tanaka

    日本化学会第92春季年会  2012.3 

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  • Chroptical property of Ag triangular nanoplate protected by chiral molcules

    Y. Kojima, N. Nishida, H. Tanaka

    EAC2011  2011.9 

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  • Size-selected Ag nanoparticle clusters deposited on carbon nanotubes

    T. Shinohara, N. Nishida, H. Tanaka

    EAC2011  2011.9 

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  • Heating process of silver nanoparticles diameter-selected by DMA

    D. Sugiura, N. Nishida, H. Tanaka

    EAC2011  2011.9 

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  • 液相レーザー蒸発法によるサイズ制御された金ナノ粒子の生成とそのカーボンナノチューブ上への担持

    遠藤貴裕, 真船文隆, 佐久間和子, 西田直樹, 田中秀樹

    第5回分子科学討論会  2011.9 

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  • Synthesis of copper nanoparticles by photochemical process

    N. Nishida, A. Miyashita, H. Tanaka

    EAC2011  2011.9 

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  • キラルチオール置換反応による光学活性三角形銀ナノプレートの合成とその不斉光学特性

    西田直樹, 小島康裕, 田中秀樹

    第5回分子科学討論会  2011.9 

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  • Chiroptical properties of Ag triangular nanoplates functionalized by chiral molecules

    西田直樹, 小島康裕, 田中秀樹

    The 9th annual Meeting of Society of Nano Science and Technology  2011.6 

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  • Production of Gold Nanoparticles by Laser Ablation in Solution and Their Deposition on Carbon Nanotubes

    ENDO, Takahiro, MAFUNE, Fumitaka, TAKAHASHI, Tomoko, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • Regenerative synthesis of copper nanoparticles by photoirradiation

    MIYASHITA, Akira, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • Protectant-free gold nanoparticles formed on carbon nanotubes

    TAKAHASHI, Tomoko, OSADA, Syohei, ENDO, Takahiro, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • Structure analysis of Ag nanoparticle clusters produced on carbon nanotubes

    SHINOHARA, Taiki, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • Synthesis of Ag triangular nanoplates protected by chiral molecules and their chiroptical properties

    KOJIMA, Yasuhiro, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • In situ structure observation of Ag nanoparticles realized by tandem analyses of differential mobility analyzer and aerosol particle mass analyzer

    HORIUCHI, Mami, SEKIGUCHI, Yasumasa, NISHIDA, Naoki, TANAKA Hideki

    日本化学会第91春季年会  2011.3 

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  • Reactivity and stability of Ag triangular nanoplates produced by substitution of surface protectants

    SAWADA, Tomoaki, KOJIMA, Yasuhiro, NISHIDA, Naoki, TANAKA, Hideki

    日本化学会第91春季年会  2011.3 

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  • Production of novel nanocolloids using gas-born Ag nanoparticles

    Naomi Hashimoto, Haruno Murayama, Naoki Nishida, Hideki Tanaka

    Pacifichem2010  2010.12 

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  • Olefin epoxidation catalyzed by shape-controlled Ag triangular nanoplates

    Haruno Murayama, Tomoaki Sawada, Naomi Hashimoto, Hideki Tanaka

    Pacifichem2010  2010.12 

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  • Synthesis and size separation of Ag triangular nanoplates by photoirradiation

    T. Sawada, H. Murayama, H. Tanaka

    IAC2010 Abstract book/International Aerosol Coference  2010.9 

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  • Efficient dimer formation of diameter-selected Ag nanoparticles

    M. Horiuchi, H. Tanaka

    IAC2010 Abstract book/International Aerosol Coference  2010.9 

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  • Production of gold nanoparticles with carbon nanotubes by|rn|laser ablation in solution

    T. Endo, F. Mafune, T. Takahashi, N. Nishida, H. Tanaka

    ISSPIC15  2010.9 

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  • Synthesis of highly reactive copper nanoparticles by photo irradiation

    A. Miyashita, H. Murayama, N. Nishida, H. Tanaka

    ISSPIC15  2010.9 

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  • Protectant-free production of gold nanoparticles with less than 2 nm diameter using carbon nanotubes

    T. Takahashi, T. Endo, N. Nishida, H. Tanaka

    ISSPIC15  2010.9 

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  • 光照射によるAg三角形ナノプレートの生成とサイズ選別

    澤田 智晶, 橋本 奈緒美, 村山 美乃, 田中 秀樹

    日本化学会第90春季年会講演予稿集,日本化学会  2010.3 

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  • Ag三角形ナノプレートによるオレフィン部分酸化反応と活性構造の解明

    村山 美乃, 澤田 智晶, 向田 篤史, 田中 秀樹

    日本化学会第90春季年会講演予稿集,日本化学会  2010.3 

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  • 混合溶液中におけるC60ナノファイバーの生成とそのサイズ制御

    大垣 匠平, 村山 美乃, 田中 秀樹

    日本化学会第90春季年会講演予稿集,日本化学会  2010.3 

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  • 粒径選別した銀ナノ粒子のカーボンナノチューブ上でのクラスター化に関する研究

    堀内 麻美, 穀野 翔, 村山 美乃, 田中 秀樹

    日本化学会第90春季年会講演予稿集,日本化学会  2010.3 

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  • イオン液体液滴中における銀ナノ粒子のクラスター化に関する研究

    関口 泰正, 村山 美乃, 田中 秀樹

    日本化学会第90春季年会講演予稿集,日本化学会  2010.3 

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  • Investigation of structure and chemical composition analysis of ionic-liquid coated Ag nanoparticles

    Y. Sekiguchi, M. Shigeyasu, H. Murayama, H. Tanaka

    Abstract book of EAC2009/Association for Aerosol Research  2009.9 

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  • Size analysis of composite nanoparticles by mixing of Ag and C60 in the gas phase

    F. Maeda, N. Hashimoto, H. Murayama, H. Tanaka

    Abstract book of EAC2009/Association for Aerosol Research  2009.9 

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  • Novel nanocolloids production using diameter-selected Ag nanoparticles formed in the gas phase

    N. Hashimoto, H. Murayama, H. Tanaka

    Abstract book of EAC2009/Association for Aerosol Research  2009.9 

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  • 粒径選別された気相生成Agナノ粒子のコロイド化に関する研究

    橋本 奈緒美, 村山 美乃, 田中 秀樹

    分子化学討論会2009講演会要旨集,分子科学会  2009.9 

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  • 超音波印加によるC60ナノファイバーの高効率生成とその構造分析

    大垣 匠平, 村山 美乃, 田中 秀樹

    分子科学討論会2009講演会要旨集,分子科学会  2009.9 

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  • 粒径選別された銀ナノ粒子の気相加熱による融解過程の観測

    河原 竜也, 橋本 奈緒美, 村山 美乃, 田中 秀樹

    分子化学討論会2009講演会要旨集,分子科学会  2009.9 

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  • 光照射により調製したAgナノプレートのシクロヘキセンエポキシ化触媒活性

    村山 美乃, 橋本 奈緒美, 田中 秀樹

    第104回触媒討論会要旨集,触媒学会  2009.9 

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  • C60蒸気下におけるAgナノ粒子クラスターの生成と構造に関する研究

    前田 太志, 橋本 奈緒美, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 粒径選別された銀ナノ粒子の気相加熱による消失過程の観測

    河原 竜也, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 粒径選別されたイオン液体ナノ粒子の生成および化学的同定

    重安 正治, 関口 泰正, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • PVP保護されたAg三角形ナノプレートの表面構造およびオレフィン部分酸化触媒作用

    村山 美乃, 橋本 奈緒美, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 光照射下における単層カーボンナノチューブ上への金ナノ粒子の生成と成長過程に関する研究

    武蔵 大輔, 中川 和早, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 光照射によるAu多角形ナノ粒子の生成とその表面構造解析

    中川 和早, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • イオン液体によって被覆された銀ナノ粒子の構造解析と生成過程に関する研究

    関口 泰正, 平沼 洋次郎, 重安 正治, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 超音波照射下におけるC60ナノファイバーの高効率生成と構造評価

    大垣 匠平, 村山 美乃, 田中 秀樹

    日本化学会第89春季年会,日本化学会  2009.3 

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  • 粒径選別された気相Agナノ粒子の液相捕獲と溶媒効果

    橋本 奈緒美, 村山 美乃, 田中 秀樹

    化学工学会第74年会,化学工学会  2009.3 

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  • Synthesis of Triangular Ag Nanocrystals by Photo-induced Reduction of AgNO3 Solution International conference

    Haruno Murayama, Hideki Tanaka

    Book of Abstracts XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)  2008.9  XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)

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  • Production of composite nanoparticles by mixing of C60 nanoparticles and Ag nanoparticles International conference

    Futoshi Maeda, Haruno Murayama, Hideki Tanaka

    Book of Abstracts XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)  2008.9  XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)

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  • Heating process of diameter-selected Ag nanoparticles using a differental mobility analyzer (DMA) International conference

    Tatsuya Kawahara, Haruno Murayama, Hideki Tanaka

    Book of Abstracts XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)  2008.9  XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)

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  • Measurement of X-ray photoelectron spectroscopy and infrared spectroscopy for diameter-selected ionic liquid nanoparticles International conference

    Masahiaru Shigeyasu, Haruno Murayama, Hideki Tanaka

    Book of Abstracts XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)  2008.9  XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)

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  • Production of Au nanoparticles deposited on carbon nanotubes by photo irradiation International conference

    Daisuke Musashi, Haruno Murayama, Hideki Tanaka

    Book of Abstracts XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)  2008.9  XIV International Symposium on Small Particles and Inorganic Clusters (ISSPIC14)

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  • 光照射によるPVP保護Ag三角形プレートの生成と結晶成長

    村山 美乃, 内田 裕貴, 田中 秀樹

    第2回分子科学討論会,分子科学会  2008.9 

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  • 粒径選別された気相生成Agナノ粒子の液相捕獲

    橋本 奈緒美, 前田 太志, 村山 美乃, 田中 秀樹

    第2回分子科学討論会,分子科学会  2008.9 

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  • 光照射による多角形Auナノ粒子の生成および化学組成分析

    中川 和早, 村山 美乃, 田中 秀樹

    第2回分子科学討論会,分子科学会  2008.9 

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  • Generation of Au nanoparticles from aurate solutions by using photochemical process International conference

    K. Nakagawa, H. Murayama, H. Tanaka

    EAC2008 Abstract  2008.8  European Aerosol Conference Gesellschaft fur Aerosolforschung

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  • Capture process of gas-born Ag nanoparticles into the liquid phase International conference

    N. Hashimoto, M. Sato, H. Murayama, H. Tanaka

    EAC2008 Abstract  2008.8  European Aerosol Conference Gesellschaft fur Aerosolforschung

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  • Structure analysis of size-controlled Ag nanoparticles for olefin epoxidation International conference

    Haruno Murayama, Hideki Tanaka

    Book of Abstracts 14th International Congress on Catalysis (14th ICC)  2008.7  14th International Congress on Catalysis (14th ICC)

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  • 粒径選別された銀ナノ粒子の金属表面への捕獲過程

    坂上 友理, 松元 崇, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • 気相中におけるC60ナノ粒子とAgナノ粒子の混合によって生成されるイオン化ナノ粒子の起源

    前田 太志, 渡邊 哲央, 橋本 奈緒美, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • 粒径選別された銀ナノ粒子の加熱による消失過程に関する研究

    河原 竜也, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • X線光電子分光法による粒径選別されたイオン液体ナノ粒子の化学構造に関する研究

    重安 正治, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • 光照射を用いたアルコール溶媒中におけるPVP保護Agナノ粒子の形状制御

    中川 和早, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • Pdナノ粒子の高分子電解質PSSによる一段階生成および粒子径制御

    殿元 真司, 村山 美乃, 田中 秀樹

    日本化学会第88春季年会,日本化学会 日本化学会  2008.3 

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  • 気相由来金属ナノ粒子の液相への捕獲過程に関する研究

    橋本 奈緒美, 佐藤 真広, 村山 美乃, 田中 秀樹

    化学工学会第73年会,化学工学会 化学工学会  2008.3 

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  • Formation process and chemical structure analysis of ionic-liquid nanoparticle International conference

    M. Shigeyasu, H. Tanaka

    EAC2007 Abstract  2007.9  European Aerosol Conference Gesellschaft fur Aerosolforschung

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  • Production of novel Ag nanoparticle with C60 nanoparticle International conference

    N. Hashimoto, S. Taguchi, H. Tanaka

    EAC2007 Abstract  2007.9  European Aerosol Conference Gesellschaft fur Aerosolforschung

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  • 高分子電解質により一段階生成される金属粒子に関する研究

    殿元 真司, 村山 美乃, 田中 秀樹

    第1回分子科学討論会2007講演要旨集,分子科学討論会 分子科学会  2007.9 

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  • 銀含有十字型粒子の生成と構造および組成分析

    後藤 大樹, 村山 美乃, 田中 秀樹

    第1回分子科学討論会2007講演要旨集,分子科学討論会 分子科学会  2007.9 

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  • 粒径選別されたイオン液体ナノ粒子の化学構造分析

    重安 正治, 村山 美乃, 田中 秀樹

    日本化学会第1回関東支部大会(2007)講演予稿集,日本化学会関東支部 日本化学会関東支部  2007.9 

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  • 気相中で生成したAg-C60複合ナノ粒子の液相捕集と組成分析

    橋本 奈緒美, 佐藤 真広, 村山 美乃, 田中 秀樹

    日本化学会第1回関東支部大会(2007)講演予稿集,日本化学会関東支部 日本化学会関東支部  2007.9 

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  • 有機分子保護ナノクラスターを前駆体としたAg触媒の調製と構造

    村山 美乃, 橋本 奈緒美, 田中 秀樹

    第100回触媒討論会 討論会A予稿集,触媒学会 触媒学会  2007.9 

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  • 金属‐フラーレン複合ナノ粒子の生成と液相粒子捕集

    橋本 奈緒美, 田口 俊, 田中 秀樹

    日本化学会第87春季年会,日本化学会 日本化学会  2007.3 

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  • C60ナノ粒子とAgナノ粒子の混合によるイオン化ナノ粒子の生成過程

    渡辺 哲央, 影澤 幸一, 田中 秀樹

    日本化学会第87春季年会,日本化学会 日本化学会  2007.3 

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  • パルスレーザー照射による液相金ナノ粒子のイオン化過程の解明

    山田 邦寛, 田中 秀樹, 永田 敬, 真船 文隆

    日本化学会第87春季年会,日本化学会 日本化学会  2007.3 

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  • 減圧下におけるイオン液体のナノ粒子生成に関する研究

    重安 正治, 田中 秀樹

    日本化学会第87春季年会,日本化学会 日本化学会  2007.3 

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  • 銀鏡反応による銀含有花形粒子の生成に関する研究

    後藤 大樹, 石川 幸代, 田中 秀樹

    日本化学会第87春季年会,日本化学会 日本化学会  2007.3 

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  • 気相中におけるAg-C60複合ナノ粒子の生成と液相中へのナノ粒子捕集

    橋本 奈緒美, 田中 秀樹

    化学工学会第72年会,化学工学会 化学工学会  2007.3 

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  • 液相中における金属‐フラーレン複合ナノ粒子の合成とサイズ選別

    橋本 奈緒美, 田中 秀樹

    分子構造総合討論会2006,分子構造総合討論会2006 分子構造総合討論会2006  2006.9 

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  • Investigation of oxidation and reduction of silver nanoparticles by size analysis International conference

    Shuji Kaneda, Hideki Tanaka

    Book of Abstracts XIII International Symposium on Small Particles and Inorganic Clusters (ISSPIC13)  2006.7  XIII International Symposium on Small Particles and Inorganic Clusters (ISSPIC13)

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  • Structure and formation process of Ag-C60 composite nanoparticle International conference

    Hideki Tanaka, Takahiro Shimamura

    Book of Abstracts XIII International Symposium on Small Particles and Inorganic Clusters (ISSPIC13)  2006.7  XIII International Symposium on Small Particles and Inorganic Clusters (ISSPIC13)

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  • Bimolecular Reactions of Nitrogen Monoxide on Cobalt Cluster Ions

    大川 隆司, 半村 哲, 市橋 正彦, 田中 秀樹, 近藤 保

    ナノ学会第4回大会講演予稿集,ナノ学会 ナノ学会  2006.5 

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  • 単一パルスレーザー照射による金微粒子の構造変化

    松尾 夏海, 田中 秀樹, 真船 文隆

    日本化学会第86春季年会,日本化学会 日本化学会  2006.3 

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  • 表面電位の制御された金ナノ粒子のレーザー励起による構造変化

    山田 邦寛, 田中 秀樹, 永田 敬, 真船 文隆

    日本化学会第86春季年会,日本化学会 日本化学会  2006.3 

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  • 気相中における金属-フラーレン複合ナノ粒子のイオン化過程

    影澤 幸一, 島村 隆博, 田中 秀樹

    日本化学会第86春季年会,日本化学会 日本化学会  2006.3 

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  • 金属-フラーレン複合ナノ粒子(Cu, Ag, Au)の生成に関する研究

    安積 麗子, 島村 隆博, 田中 秀樹

    日本化学会第86春季年会,日本化学会 日本化学会  2006.3 

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  • 銀-フラーレン複合ナノ粒子の構造と生成機構の解明

    島村 隆博, 田中 秀樹

    日本化学会第86春季年会,日本化学会 日本化学会  2006.3 

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  • Structural analysis of structure-controlled gold nanoparticle produced by irradiation of pulse laser International conference

    Kunihiro Yamada, Hideki Tanaka, Fumitaka Mafune

    Pacifichem2005  2005.12  Pacifichem2005 Pacifichem2005

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  • 単一パルスレーザー照射による金属微粒子の構造変化

    松尾 夏海, 田中 秀樹, 真船 文隆

    分子構造総合討論会2005,分子構造総合討論会2005 分子構造総合討論会2005  2005.9 

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  • ナノ秒過渡吸収スペクトル測定による金ナノ粒子のレーザー微小化機構の解明

    山田 邦寛, 田中 秀樹, 永田 敬, 真船 文隆

    分子構造総合討論会2005,分子構造総合討論会2005 分子構造総合討論会2005  2005.9 

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  • 粒径選別されたAgナノ粒子の化学形態分析

    金田 秀治, 関 信, 田中 秀樹

    分子構造総合討論会2005,分子構造総合討論会2005 分子構造総合討論会2005  2005.9 

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  • Investigation of size-selected silver nanoparticle by using X-ray photoelectron spectroscopy International conference

    Hideki Tanaka, Makoto Seki, Takahiro Shimamura

    EAC2005(European Aerosol Conference 2005)  2005.8  Willy Maenhaut EAC2005(European Aerosol Conference 2005)

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  • パルスレーザー照射により構造制御された金ナノ粒子の構造解析

    山田 邦寛, 田中 秀樹, 真船 文隆

    日本化学会第85春季年会,日本化学会第85春季年会 日本化学会  2005.3 

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  • 銀含有フラーレン複合ナノ粒子の生成に関する研究

    島村 隆博, 貴志 知子, 関 信, 田中 秀樹

    日本化学会第85春季年会,日本化学会第85春季年会 日本化学会  2005.3 

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  • Diameter determination of fullerene particles using a differential mobility analyzer International conference

    H. Tanaka, K. Takeuchi

    European Aerosol Conference EAC-2004 Post Deadline Abstracts  2004.9  European Aerosol Conference European Aerosol Conference

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  • コロナ放電下にて生成される酸化物フラーレンクラスターに関する研究

    田中 秀樹, 武内 一夫, 根岸 雄一, 佃 達哉

    分子構造総合討論会2004,分子構造総合討論会2004 分子構造総合討論会2004  2004.9 

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  • Calibration of differential mobility analyzer by use of a C60 monomer as an inherently monodisperse standard nanoparticle International conference

    Hideki Tanaka, Kazuo Takeuchi

    Book of Abstracts 22nd Annual AAAR Conference  2003.10  American Asoociation for Aerosol Research (AAAR)

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  • Electrical Mobilities of C60 Monomer and C60 Oligomers Formed under Low Pressure International conference

    Kazuo Takeuchi, Hideki Tanaka

    EAC2003  2003.9  Elsevier Gesellschaft fur Aerosolforschung

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  • 大気圧イオン化法により生成されるフラーレンクラスターの構造に関する研究

    田中秀樹, 彼島俊宏, 長本英俊, 根岸雄一, 佃達哉, 武内一夫

    2002 分子構造総合討論会 講演要旨集,日本化学会  2002.10 

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  • Differential mobility analysis of C60 monomer and [2+2] C60 dimer International conference

    H. Tanaka, K. Takeuchi

    Book of Abstracts 11th International Symposium on Small Particles and Inorganic Clusters (ISSPIC11)  2002.9  11th International Symposium on Small Particles and Inorganic Clusters (ISSPIC11)

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  • ナノ領域における標準粒子としてのフラーレンクラスターに関する研究

    田中秀樹, 武内一夫

    第19回エアロゾル科学・技術研究討論会,日本エアロゾル学会  2002.8 

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  • 気相中におけるフラーレン重合体の生成とその構造に関する研究

    田中秀樹, 武笠夏子, 松本史朗, 武内一夫

    The 13th Symposium of The Materials Research Society of Japan - Program and Abstracts,The Materials Research Society of Japan (MRS-J)  2001.12 

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  • 気相蒸発法により生成されるフラーレンクラスターの構造に関する研究

    田中秀樹, 武笠夏子, 松本史朗, 武内一夫

    2001 分子構造総合討論会 講演要旨集,日本化学会  2001.9 

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  • 電気移動度測定によるフラーレンナノクラスター生成に関する研究

    田中秀樹, 武内一夫

    日本化学会第79春季年会 講演予稿集,日本化学会  2001.3 

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  • In situ XPSを用いたSi蒸着C60薄膜に関する研究

    田中秀樹, 尾上順, 原寿樹, 武内一夫

    The 12th Symposium of The Materials Research Society of Japan - Program and Abstracts,The Materials Research Society of Japan (MRS-J)  2000.12 

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  • In situ XPS study of the interaction between Si and C60 International conference

    H. Tanaka, J. Onoe, K. Takeuchi

    Book of Abstracts 10th International Symposium on Small Particles and Inorganic Clusters (ISSPIC10)  2000.10  10th International Symposium on Small Particles and Inorganic Clusters (ISSPIC10)

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  • 新規フラーレン合成を目的とした異種原子導入C60薄膜に関する研究

    田中秀樹, 尾上順, 原寿樹, 武内一夫

    第3回コヒーレント科学シンポジウム,理化学研究所  2000.1 

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  • FTIRおよびFTMSによる電子ビーム照射によるC60固相反応の検討

    原寿樹, 尾上順, 田中秀樹, 武内一夫

    第3回コヒーレント科学シンポジウム,理化学研究所  2000.1 

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  • MxC60 混合薄膜(M=Si, Ti)に関する研究

    田中秀樹, 尾上順, 原寿樹, 武内一夫

    第11回日本MRS学術シンポジウム プログラム・要旨集,The Materials Research Society of Japan (MRS-J)  1999.12 

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  • 異種原子をドープしたフラーレン薄膜における化学反応

    田中秀樹, 尾上順, 原寿樹, 武内一夫

    金研ワークショップ「実験と計算科学的アプローチの共同によるナノ物質研究」,東北大学 金属材料研究所  1999.11 

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  • 電子ビーム照射により誘起されるC60固体内の化学反応

    原寿樹, 尾上順, 田中秀樹, 大澤秀一, 武内一夫

    金研ワークショップ「実験と計算科学的アプローチの共同によるナノ物質研究」,東北大学 金属材料研究所  1999.11 

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  • フラーレン-シリコン混合薄膜中における化学反応に関する研究

    田中秀樹, 尾上順, 原寿樹, 中尾愛子, 武内一夫

    1999 分子構造総合討論会 講演要旨集,日本化学会  1999.9 

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  • Investigation of the interaction between C60 and Si atoms International conference

    H. Tanaka, J. Onoe, T. Hara, A. Nakao, K. Takeuchi

    10th international symposium on intercalation compounds (ISIC10)  1999.6  ISIC

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  • Kinetics study of an electron-beam induced reaction of C60 film by in situ FT-IR spectroscopy International conference

    T. Hara, J. Onoe, H. Tanaka, K. Takeuchi

    10th international symposium on intercalation compounds (ISIC10)  1999.6  ISIC

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  • 光電子分光法を用いたシリコンとフラーレンの相互作用に関する研究

    田中秀樹, 尾上順, 原寿樹, 中尾愛子, 武内一夫

    超微粒子とクラスター懇談会 第3回研究会講演予稿集,超微粒子とクラスター懇談会  1999.5 

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  • 電子ビーム照射C60薄膜のin situ FT-IR分光

    尾上順, 原寿樹, 田中秀樹, 武内一夫

    超微粒子とクラスター懇談会 第3回研究会講演予稿集,超微粒子とクラスター懇談会  1999.5 

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  • 光誘起反応を用いたSi付着フラーレンの合成

    田中秀樹, 原寿樹, 尾上順, 武内一夫

    日本化学会第76春季年会 講演予稿集,日本化学会  1999.3 

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  • XPSによるSi付着C60薄膜に関する研究

    田中秀樹, 尾上順, 原寿樹, 中尾愛子, 武内一夫

    第2回コヒーレント科学シンポジウム,理化学研究所  1999.2 

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  • C60薄膜の電子ビーム照射(その3):In situ赤外分光による反応速度解析

    原寿樹, 尾上順, 田中秀樹, 武内一夫

    第16回フラーレン総合シンポジウム講演要旨集,フラーレン研究会  1999.1 

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  • C60とSiの相互作用に関する研究

    田中秀樹, 原寿樹, 尾上順, 武内一夫

    第16回フラーレン総合シンポジウム講演要旨集,フラーレン研究会  1999.1 

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  • シリコン被覆フラーレンに関する研究

    田中秀樹, 原寿樹, 大澤秀一, 尾上順, 武内一夫

    金研ワークショップ「実験と計算科学的アプローチの共同によるナノ物質研究」,東北大学 金属材料研究所  1998.10 

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  • Reaction Dynamics of Sodium Cluster Ions with SF6: Selective Formation of Na2F+ International conference

    H. Tanaka, T. Hanmura, M. Ichihashi, T. Kondow

    Book of Abstracts 9th International Symposium on Small Particles and Inorganic Clusters (ISSPIC9)  1998.9  ISSPIC

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  • 半経験的分子軌道法を用いたC60Sinクラスターの生成熱の計算

    田中秀樹, 大澤秀一, 尾上順, 武内一夫

    第15回フラーレン総合シンポジウム,フラーレン研究会  1998.7 

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  • NOクラスター負イオンと原子・分子の衝突過程

    山口仁志, 田中秀樹, 市橋正彦, 安松久登, 寺嵜亨, 近藤保

    日本化学会第74春季年会 講演予稿集,日本化学会  1998.3 

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  • Low-Energy Collision Processes of Sodium Cluster Ions International conference

    H. Tanaka, T. Hanmura, S. Nonosei, T. Kondow

    Abstracts Book of International Symposium Similarities and differences between atomicnuclei and -clusters  1997.7  Tsukuba University

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  • Collisional Dissociation of Na9+ with Rare-Gas Atoms International conference

    H. Tanaka, T. Hanmura, M. Ichihashi, T. Kondow

    XVII International Symposium on Molecular Beams Book of abstracts  1997.6  Paris XI University

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  • ナトリウムクラスターイオンの衝突反応過程

    田中秀樹, 半村哲, 野々瀬真司, 近藤保

    日本化学会第72春季年会 講演予稿集,日本化学会  1997.3 

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  • アルカリ金属クラスターイオンの反応性-電子構造と衝突解離ダイナミクス

    田中秀樹, 水野智之, 石崎史彦, 半村哲, 野々瀬真司, 近藤保

    1996 分子構造総合討論会講演要旨集,日本化学会  1996.10 

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  • ナトリウムクラスターイオンと含酸素分子との反応性衝突

    田中秀樹

    京都大学基礎物理学研究所1996年研究会,京都大学基礎物理学研究所  1996.8 

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  • アルカリ金属クラスターイオンの衝突反応過程

    田中秀樹, 水野智之, 石崎史彦, 野々瀬真司, 近藤保

    第12回 化学反応討論会講演要旨集,化学反応討論会プログラム委員会  1996.5 

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  • 高沸点金属クラスターイオンの生成と反応

    水野智之, 田中秀樹, 石崎史彦, 野々瀬真司, 近藤保

    日本化学会第70春季年会 講演予稿集,日本化学会  1996.3 

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  • ナトリウムクラスターイオンの酸化反応過程

    田中秀樹, 水野智之, 石崎史彦, 野々瀬真司, 近藤保

    日本化学会第70春季年会 講演予稿集,日本化学会  1996.3 

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  • ナトリウムクラスターイオンと気体分子との衝突反応

    田中秀樹, 水野智之, 石崎史彦, 野々瀬真司, 近藤保

    理研シンポジウム「クラスター科学の展望'95」,理化学研究所  1996.1 

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  • 金属クラスターイオンの電子構造と衝突解離ダイナミクス

    田中秀樹, 水野智之, 金南俊, 野々瀬真司, 近藤保

    1995 分子構造総合討論会講演要旨集,日本化学会  1995.9 

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  • ナトリウムクラスターイオンの衝突過程とダイナミクス

    野々瀬真司, 田中秀樹, 水野智之, 廣川淳, 近藤保

    京都大学基礎物理学研究所1995年研究会,京都大学基礎物理学研究所  1995.8 

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  • Dynamics on Dissociation of Sodium Cluster Ions by He Impact International conference

    H. Tanaka, T.Mizuno, J. Hirokawa, S. Nonose, T. Kondow

    Yamada Conference XLIII Book of Abstracts  1995.5  Yamada Conference

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  • ナトリウムクラスターイオンの衝突過程とダイナミクス

    野々瀬真司, 田中秀樹, 水野智之, 金南俊, 廣川淳, 近藤保

    第11回 化学反応討論会講演要旨集,化学反応討論会プログラム委員会  1995.5 

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  • ナトリウムクラスターイオンの衝突解離反応

    田中秀樹, 水野智之, 廣川淳, 野々瀬真司, 近藤保

    日本化学会第69春季年会 講演予稿集,日本化学会  1995.3 

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  • ナトリウムクラスターイオンの衝突解離断面積測定

    田中秀樹, 水野智之, 廣川淳, 野々瀬真司, 近藤保

    原子衝突研究教会 第19回研究会,原子衝突研究協会  1994.10 

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  • ナトリウムクラスターイオンの衝突過程

    田中秀樹, 水野智之, 廣川淳, 野々瀬真司, 近藤保

    1994 分子構造総合討論会講演要旨集,日本化学会  1994.9 

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  • ナトリウムクラスターイオンの衝突反応過程

    田中秀樹, 廣川淳, 野々瀬真司, 近藤保

    第10回 化学反応討論会講演要旨集,化学反応討論会プログラム委員会  1994.6 

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  • クラスターイオンの衝突過程

    野々瀬真司, 廣川淳, 市橋正彦, 田中秀樹, 永田敬, 近藤保

    第10回 化学反応討論会講演要旨集,化学反応討論会プログラム委員会  1994.6 

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  • クラスターイオンの衝突誘起解離反応

    廣川淳, 市橋正彦, 田中秀樹, 野々瀬真司, 永田敬, 近藤保

    第9回 化学反応討論会講演要旨集,化学反応討論会プログラム委員会  1993.6 

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  • サイズを選別したメタノールクラスターイオンの衝突誘起過程

    田中秀樹, 野々瀬真司, 永田敬, 近藤保

    日本化学会第65春季年会 講演予稿集,日本化学会  1993.3 

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  • 分子クラスターイオンの衝突誘起反応

    坂本将俊, 田中秀樹, 野々瀬真司, 近藤保

    1992 分子構造総合討論会講演要旨集,日本化学会  1992.9 

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Awards

  • Inoue Research Award for Young Scientists

    2000.2   Inoue Foundation for Science   クラスターイオンの衝突反応過程

    田中 秀樹

Research Projects

  • 形状、粒径、物性に多様性を持った貴金属ライクな純銅ナノ粒子の触媒への応用

    Grant number:19K05187  2019.4 - 2023.3

    日本学術振興会  学術研究助成基金  基盤研究(C) 

    田中 秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \4420000 ( Direct Cost: \3400000 、 Indirect Cost: \1020000 )

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  • 再生利用可能な純銅ナノ粒子の環境触媒への展開

    2019.1 - 2021.12

    JFE21世紀財団  技術研究助成 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \2000000 ( Direct Cost: \2000000 )

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  • 複数の元素からなる多元素クラスターの反応性および構成原理の解明と実用触媒への展開

    2013.4 - 2016.3

    文部科学省  科学研究費補助金(日本学術振興会・文部科学省)-基盤研究(A) 

    真船 文隆

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    Grant type:Competitive

    Grant amount: \5200000 ( Direct Cost: \4000000 、 Indirect Cost: \1200000 )

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  • 粒径制御金属ナノ粒子を用いた新規ナノ構造体の創製とその触媒作用に関する研究

    2009.6 - 2010.5

    (財)東京応化科学技術振興財団  民間助成金 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \800000

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  • バイオ分子分離技術を応用した1原子レベルでサイズ制御されたフラーレン複合ナノ粒子の創成

    2007.4 - 2008.3

    理工学研究所 研究プロジェクト 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \1400000

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  • 自動車排出ナノ粒子のモニタリング技術の開発

    2003.10 - 2006.9

    NEDO  公的機関からの助成金(私大助成等) 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \30537000

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  • フラーレン重合体の創製と「ナノメートル原器」への応用に関する研究

    2005.4 - 2006.3

    中央大学  中央大学特定課題研究費 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \1246000

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  • 「ナノメートル原器」創製のための単分散標準粒子の発生に関する研究

    Grant number:15710098  2003 - 2005

    日本学術振興会  科学研究費助成事業  若手研究(B) 

    田中 秀樹

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    Grant amount: \2700000 ( Direct Cost: \2700000 )

    ナノスケール領域において顕著に発現されると期待されている量子サイズ効果は、ナノ物質のサイズ(あるいはナノ粒子の粒径)に極めて敏感であるため、そのサイズを精確に決定することが必要不可欠である。しかし従来から行われている外挿法に基づく方法ではこうしたことは実現不可能であった。そこで本研究では、「ナノメートル原器」とも呼ぶべき単分散なナノ標準粒子の系統的な発生法の確立を目的とした検討を行った。
    平成17年度は、前年度開発を行ったコロナ放電型ナノ粒子凝集装置およびナノ粒子発生源を用いて、1〜10nm域における単分散標準粒子の系統的発生法について検討を行った。コロナ放電型ナノ粒子凝集装置を用いたところ、放電電流強度に依存したフラーレンナノ粒子粒径分布スペクトルが得られた。分析装置(DMA)の粒径選別分解能を高めて測定を行ったところ、10量体まで重合したフラーレンナノ粒子のスペクトルが、それぞれ他のサイズから単離して観測されることがわかった。このことは、フラーレンナノ粒子を用いることによって、10量体まではナノ定規の目盛りのように扱うことができることを示唆している。一方、その構造について計算機シミュレーションによる予測を行った。その結果、小さなサイズのフラーレンナノ粒子においては直線型の幾何構造が安定であるのに対して、大きなサイズにおいては球形に凝集した形状が安定であることが示された。一方、ナノ粒子発生源において、フラーレンナノ粒子を金属蒸気(銀など)中を通過させることによって得られるナノ粒子についても調べた。その結果、フラーレンナノ粒子の粒径に強く依存する5〜10nmの粒径をもつ金属フラーレン複合ナノ粒子を生成することがわかった。このナノ粒子の粒径は金属蒸気の発生条件によらず非常に一定の値を示すことから、これらの複合ナノ粒子についてもナノメートル原器としての応用が期待される。

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  • フラーレンを利用した「ナノメートル原器」創成に関する研究

    2003.4 - 2004.3

    理化学研究所  その他 

    田中秀樹

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount: \2000000

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  • 超高真空下における新規フラーレン化合物の合成とその反応機構に関する研究

    Grant number:11740396  1999 - 2000

    日本学術振興会  科学研究費助成事業  奨励研究(A)  理化学研究所

    田中 秀樹

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    Grant amount: \1900000 ( Direct Cost: \1900000 )

    アルカリ金属をドープしたフラーレンにおいて高温超伝導が発見されて以来、フラーレンを骨格にもつフラーレン重合体あるいはヘテロ原子と結合したフラーレンの示す特異な物性が新世代材料として注目されている。しかしそうしたフラーレン化合物の効率的な合成法は未だ確立されていない。本研究では、フラーレンの超薄膜化技術を利用した新規フラーレン化合物の合成法の確立、およびその反応機構の解明を目指す。
    平成12年度は、反応の"その場"観測装置を立ち上げ、測定結果の定量的解析によるフラーレン薄膜内反応の反応機構の解明を行った。具体的には、(1)C_<60>薄膜内反応のその場観測、および(2)C_<60>-Si混合薄膜内反応のその場観測を行った。またこれと平行して、(3)非対称型フラーレン,C_<70>,の反応への応用の検討も行った。(1)の研究においては、低エネルギー(1keV)電子線衝撃によるC_<60>重合体生成反応の反応速度定数をin situ FTIR測定による実験から求めた。その結果、重合反応は照射量に対して非線形的に進行することを見いだした。また(2)の研究においては、C_<60>と原子状Siの混合により高効率にて反応錯合体が形成されることを見いだした。実際、C_<60>に対し4倍量のSiを混合した薄膜においてほぼ100%の反応生成物が観測された。一方、(3)の研究においては、フラーレンの非対称型化による著しい反応効率の低下が観測された。これは反応に主として関与するフラーレン上の6/6結合部の電子密度が、非対称化により低下することに起因すると考えられる。以上、本研究から、反応はフラーレンを介した電子の授受によって引き起こされること、原子状Siとの混合状態の生成が新規フラーレン合成には重要であること、の知見を得た。

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Intellectual property rights

  • 微粒子分級装置

    田中 秀樹,岡田 芳樹

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    Application no:特願2006-143388  Date applied:2006.5.23

    Announcement no:特開2007-315817  Date announced:2007.12.6

    Registration no:特許第4732952号  Date registered:2011.4.28 

    Applicant (Organization):学校法人中央大学、学校法人関西大学

  • 複合フラーレン粒子の製造方法、その製造装置及び複合フラーレン粒子

    田中 秀樹,島村 隆博,関 信,貴志 知子,安積 麗子

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    Application no:特願2006-043715  Date applied:2006.2.21

    Announcement no:特開2006-265089  Date announced:2006.10.5

    Registration no:特許第5099298号  Date registered:2012.10.5 

    Applicant (Organization):タマティーエルオー株式会社

Committee Memberships

  • 2019.9 - 2022.8

    分子科学会   編集委員長  

  • 2012.9 - 2019.8

    分子科学会   編集委員  

Academic Activities

  • 日本化学会第104春季年会 プログラム編成会 編成委員

    Role(s): Planning, management, etc.

    The Chemical Society of Japan  2023.9 - 2024.3

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  • 日本化学会第103春季年会 プログラム編成会 編成委員

    Role(s): Planning, management, etc.

    The Chemical Society of Japan  2022.9 - 2023.3

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  • ナノ学会第16回大会実行委員会委員

    Role(s): Planning, management, etc.

    2017.11 - 2018.5

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  • 日本化学会第97春季年会 プログラム編成会 編成委員

    Role(s): Planning, management, etc.

    2016.12 - 2017.3

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